Promotion of the Water-Gas-Shift Reaction by Nickel Hydroxyl Species in Partially Reduced Nickel-Containing Phyllosilicate Catalysts

被引：80

作者：

Ashok, Jangam ^{[1
]}

Li Ang, Ming ^{[1
]}

Terence, Puar Zhi Liang ^{[1
]}

Kawi, Sibudjing ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem & Biomol Engn, 4 Engn Dr 4, Singapore 119260, Singapore

来源：

CHEMCATCHEM | 2016年 / 8卷 / 07期

关键词：

hydrogen; nickel; reduction; silicates; surface chemistry; SUPPORTED PLATINUM CATALYSTS; TAR MODEL-COMPOUND; LOW-TEMPERATURE; BIMETALLIC CATALYSTS; METHANE SUPPRESSION; REACTION-MECHANISM; RH/CEO2; CATALYSTS; NI/SIO2; MESOPOROUS CERIA; CO ADSORPTION;

D O I：

10.1002/cctc.201501284

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The role of surface hydroxyl species generated by partially reduced Ni-containing phyllosilicate structures (Ni/SiO2P) in promoting the water-gas-shift (WGS) reaction and methane suppression was investigated. To analyze the effect of the surface hydroxyl species, Ni/SiO2P catalysts reduced at various temperatures were employed. All the Ni/SiO2P catalysts showed enhanced catalytic performances and methane suppression compared to the conventional Ni/SiO2 catalyst. As revealed by diffuse-reflectance infrared Fourier transform spectroscopy (DRIFTS), methane suppression could be attributed to the inhibition of the formation of nickel subcarbonyl species, and the promotion of WGS activity was attributed to the involvement of surface hydroxyl species (Ni-OH, 3626cm(-1), and Si-OH, 3740cm(-1)). The Ni/SiO2P catalyst reduced at 600 degrees C showed exceptionally superior performance to the other catalysts in the water-gas-shift reaction in terms of turnover frequency (2.79s(-1)) and hydrogen formation rates (492.63mol H(2)g(-1)s(-1)) at 375 degrees C.

引用

页码：1308 / 1318

页数：11

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