Separation of isomeric polycyclic aromatic hydrocarbons by GC-MS: Differentiation between isomers by positive chemical ionization with ammonia and dimethyl ether as reagent gases

被引:8
作者
Riahi, K [1 ]
Sellier, N [1 ]
机构
[1] Ecole Natl Super Chim Paris, Lab Spect Masse, F-75231 Paris 05, France
关键词
gas chromatography-mass spectrometry; positive-ion chemical ionization (PICI); dimethyl ether and ammonia reagent gases; polycyclic aromatic hydrocarbons (PAHs);
D O I
10.1007/BF02466537
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Sixteen PAHs have been separated by GC-MS and some isomeric PAHs were differentiated by positive-ion chemical ionization (PICI) using two different reagent gases, ammonia and dimethyl ether. Differentiation, which was better with DME, was possible on the basis of the identities and relative abundances of the adduct ions.
引用
收藏
页码:309 / 312
页数:4
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