Functionalization of polymeric materials as a high performance membrane for direct methanol fuel cell: A review

被引：102

作者：

Awang, N. ^{[1
,2
]}

Ismail, A. F. ^{[1
,2
]}

Jaafar, J. ^{[1
,2
]}

Matsuura, T. ^{[1
,3
]}

Junoh, H. ^{[1
,2
]}

Othman, M. H. D. ^{[1
,2
]}

Rahman, M. A. ^{[1
,2
]}

机构：

[1] Univ Teknol Malaysia, Adv Membrane Technol Res Ctr AMTEC, Utm Skudai 81310, Johor Bahru, Malaysia

[2] Univ Teknol Malaysia, Fac Petr & Renewable Energy Engn, Utm Skudai 81310, Johor Bahru, Malaysia

[3] Univ Ottawa, Dept Chem Engn, Ottawa, ON K1N 6N5, Canada

来源：

REACTIVE & FUNCTIONAL POLYMERS | 2015年 / 86卷

关键词：

Functionalization; Proton exchange membranes; Direct methanol fuel cell; Electra spinning; PROTON-EXCHANGE MEMBRANE; ELECTROLYTE MEMBRANES; COMPOSITE MEMBRANES; BLENDS; NANOFIBERS; DMFC; PBI; POLYELECTROLYTES; MORPHOLOGY; STATE;

D O I：

10.1016/j.reactfunctpolym.2014.09.019

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A coherent review on the advanced proton exchange membranes (PEMs) for direct methanol fuel cell (DMFC) application and the future direction in the development of a high performance polymeric membrane for DMFC were discussed in this paper. PEMs have a profound influence on performance of DMFC. The PEMs are categorized into five groups which are partially fluorinated, perfluorinated ionomers, acid-base complexes, non-fluorinated ionomers, hydro carbon and aromatic polymers. Many researchers have investigated the functionalization methods on the PEMs to solve methanol crossover problem while obtaining low electronic conductivity, high proton conductivity, low electro osmotic drag coefficient, high mechanical properties and good chemical and thermal stability. Including in this review, fabrication of PEM using electrospinning process coupled with the promising functionalized polymeric materials which were known to be the most important initiatives at present in order to further expand the full potential of DMFC performance. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：248 / 258

页数：11

共 80 条

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