Molecular recognition of 7-(2-octadecyloxycarbonylethyl)guanine to cytidine at the air/water interface and LB film studied by Fourier transform infrared spectroscopy

被引：14

作者：

Miao, WE ^{[1
]}

Luo, XH ^{[1
]}

Liang, YQ ^{[1
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Lab Mesoscop Mat Sci, Nanjing 210093, Peoples R China

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2003年 / 59卷 / 05期

基金：

中国国家自然科学基金;

关键词：

guanine; cytidine; recognition; monolayer; FTIR spectroscopy;

D O I：

10.1016/S1386-1425(02)00292-5

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Monolayer behavior of a nucleolipid amphiphile, 7-(2-octadecyloxycarbonylethyl)guanine (ODCG), on aqueous cytidine solution was investigated by means of surface-molecular area (pi-A) isotherms. It indicates that molecular recognition by hydrogen bonding is present between ODCG monolayer and the cytidine in subphase. The Fourier transform infrared (FTIR) transmission spectroscopic result indicates that the cytidine molecules in the subphase can be transferred onto solid substrates by Langmuir-Blodgett (LB) technique as a result of the formation of Watson-Crick base-pairing at the air/water interface. Investigation by rotating polarized FTIR transmission also suggests that the headgroup recognition of this amphiphile to the dissolved cytidine influence the orientation of the tailchains. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：1045 / 1050

页数：6

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