The Low-Field Pulsed Mode Dynamic Nuclear Polarization in the Pentavalent Chromium Complex and Crude Oils

被引：23

作者：

Alexandrov, A. S. ^{[1
]}

Archipov, R. V. ^{[1
]}

Ivanov, A. A. ^{[1
]}

Gnezdilov, O. I. ^{[1
]}

Gafurov, M. R. ^{[1
]}

Skirda, V. D. ^{[1
]}

机构：

[1] Kazan Fed Univ, Inst Phys, Kazan 420008, Russia

来源：

APPLIED MAGNETIC RESONANCE | 2014年 / 45卷 / 11期

关键词：

OVERHAUSER DNP; PARAMAGNETIC-RESONANCE; HYPERPOLARIZATION; RADICALS; WATER;

D O I：

10.1007/s00723-014-0606-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Measurements of the enhancement of the proton resonance signal right after applying the radiofrequency pulse with the variable duration in the magnetic field of about 100 Gauss on the homebuilt prototype of the dynamic nuclear polarization (DNP) spectrometer at near room temperature are presented. A dependence of the DNP enhancement of the solvent protons of the solution of the pentavalent chromium complex in ethylene glycol on the pumping pulse duration and incident pumping power is given. No DNP effect on the native protons of the crude oils and natural bitumen from the Russian oilfields is observed. A miserable DNP enhancement is registered on the protons of toluene by dissolving the crude oil and bitumen samples. The perspectives of using the results and technical solutions for geological exploration, studies of the asphaltene structures and their dynamics are discussed.

引用

页码：1275 / 1287

页数：13

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