Poly[[aqua[μ-1,4-bis(3-pyridylmethyl)piperazine-κ2N:N′](μ-isophthalato-κ2O1:O3)copper(II)]

被引：0

作者：

Gandolfo, Chaun M. ^{[1
]}

LaDuca, Robert L. ^{[1
]}

机构：

[1] Michigan State Univ, Dept Chem, Lyman Briggs Coll, E Lansing, MI 48825 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

Data-to-parameter ratio = 13.2; Mean σ(C-C) = 0.004 Å; R factor = 0.043; Single-crystal X-ray study; T = 173 K; WR factor = 0.117;

D O I：

10.1107/S160053681000632X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Cu(C8H4O4)(C16H20N4)(H2O)](n), square-pyramidally coordinated Cu-II ions are linked into [Cu(H2O)(isophthalate)](n) coordination polymer chains by isophthalate dianions. These chains are connected into undulating [Cu(H2O)(isophthalate)(3-bpmp)](n) [3-bmp is bis(3-pyridylmethyl)piperazine] layers by 3-bpmp tethering ligands. The pseudo three-dimensional structure of the title compound is fostered by interlayer O-H center dot center dot center dot O hydrogen bonding between the aqua ligands and unligated isophthalate O atoms. The selected crystal was non-merohedrally twinned. Only reflections from the major twin component were used in the solution and refinement.

引用

页码：M318 / U3713

页数：13

共 7 条

[1]

[Anonymous], APEX2 SAINT

[2] One- and two-dimensional copper benzenedicarboxylate coordination polymers incorporating the flexible tethering diimine N,N′-bis(3-pyridylmethyl) piperazine:: Synthesis, structure, and thermal properties [J].

Johnston, Lindsey L. ;

Martin, David P. ;

Supkowski, Ronald M. ;

LaDuca, Robert L. .

INORGANICA CHIMICA ACTA, 2008, 361 (9-10) :2887-2894

[3]

Palmer D., 2007, CRYSTALMAKER

[4] Molecular tectonics: on the role of counter-ions in the dimensionality of silver coordination networks [J].

Pocic, D ;

Planeix, JM ;

Kyritsakas, N ;

Jouaiti, A ;

Hosseini, MW .

CRYSTENGCOMM, 2005, 7 :624-628

[5]

Sheldrick G.M., 2003, TWINABS

[6] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

[7]

SHELDRICK GM, 2009, CELLNOW

← 1 →