Solid state p-type dye-sensitized solar cells: concept, experiment and mechanism

被引：45
作者：
Zhang, Lei [1 ]
Boschloo, Gerrit [1 ]
Hammarstrom, Leif [1 ]
Tian, Haining [1 ]
机构：
[1] Uppsala Univ, Phys Chem, Dept Chem, Angstrom Lab, BOX 523, SE-75120 Uppsala, Sweden
来源：
PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2016年 / 18卷 / 07期
关键词：
ORGANIC CHROMOPHORES; NIO; COMPLEXES; PHOTOCATHODES; ELECTROLYTES; PERFORMANCE; DERIVATIVES; ABSORPTION; EFFICIENCY; DESIGN;
D O I：
10.1039/c5cp05247e
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Solid state p-type dye-sensitized solar cells (p-ssDSCs) have been proposed and fabricated for the first time, using the organic dye P1 as the sensitizer on mesoporous NiO and phenyl-C61-butyric acid methyl ester (PCBM) as the electron conductor. The p-ssDSC has shown an impressive open circuit photovoltage of 620 mV. Femto-second and nanosecond transient absorption spectroscopy has given evidence for sub-ps hole injection from the excited P1 to NiO, followed by electron transfer from P1(center dot-) to PCBM.
引用
收藏
页码：5080 / 5085
页数：6
相关论文
共 35 条
[1]   Stark Effects after Excited-State Interfacial Electron Transfer at Sensitized TiO2 Nanocrystallites [J].
Ardo, Shane ;
Sun, Yali ;
Staniszewski, Aaron ;
Castellano, Felix N. ;
Meyer, Gerald J. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (19) :6696-6709
[2]   Charge separation and fullerene triplet formation in blend films of polyfluorene polymers with [6,6]-phenyl C61 butyric acid methyl ester [J].
Benson-Smith, Jessica J. ;
Ohkita, Hideo ;
Cook, Steffan ;
Durrant, James R. ;
Bradley, Donal D. C. ;
Nelson, Jenny .
DALTON TRANSACTIONS, 2009, (45) :10000-10005
[3]   Characterization of the Interface Properties and Processes in Solid State Dye-Sensitized Solar Cells Employing a Perylene Sensitizer [J].
Cappel, Ute B. ;
Smeigh, Amanda L. ;
Plogmaker, Stefan ;
Johansson, Erik M. J. ;
Rensmo, Hakan ;
Hammarstrom, Leif ;
Hagfeldt, Anders ;
Boschloo, Gerrit .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (10) :4345-4358
[4]   The Influence of Local Electric Fields on Photoinduced Absorption in Dye-Sensitized Solar Cells [J].
Cappel, Ute B. ;
Feldt, Sandra M. ;
Schoeneboom, Jan ;
Hagfeldt, Anders ;
Boschloo, Gerrit .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (26) :9096-9101
[5]   Highly Efficiency p-Type Dye Sensitized Solar Cells Based on Polygonal Star-morphology Cu2O Material of Photocathodes [J].
Du Sisi ;
Cheng Pengfei ;
Sun Peng ;
Wang Biao ;
Cai Yaxin ;
Liu Fengmin ;
Zheng Jie ;
Lu Geyu .
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2014, 30 (04) :661-665
[6]   Diketopyrrolopyrrole derivatives for efficient NiO-based dye-sensitized solar cells [J].
Favereau, Ludovic ;
Warnan, Julien ;
Pellegrin, Yann ;
Blart, Errol ;
Boujtita, Mohammed ;
Jacquemin, Denis ;
Odobel, Fabrice .
CHEMICAL COMMUNICATIONS, 2013, 49 (73) :8018-8020
[7]   Long-Lived Charge Separated State in NiO-Based p-Type Dye-Sensitized Solar Cells with Simple Cyclometalated Iridium Complexes [J].
Gennari, Marcello ;
Legalite, Florent ;
Zhang, Lei ;
Pellegrin, Yann ;
Blart, Errol ;
Fortage, Jerome ;
Brown, Allison M. ;
Deronzier, Alain ;
Collomb, Marie-Noelle ;
Boujtita, Mohammed ;
Jacquemin, Denis ;
Hammarstrom, Leif ;
Odobel, Fabrice .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2014, 5 (13) :2254-2258
[8]   Cobalt Polypyridyl-Based Electrolytes for p-Type Dye-Sensitized Solar Cells [J].
Gibson, Elizabeth A. ;
Smeigh, Amanda L. ;
Le Pleux, Loic ;
Hammarstrom, Leif ;
Odobel, Fabrice ;
Boschloo, Gerrit ;
Hagfeldt, Anders .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (19) :9772-9779
[9]   A p-Type NiO-Based Dye-Sensitized Solar Cell with an Open-Circuit Voltage of 0.35 V [J].
Gibson, Elizabeth A. ;
Smeigh, Amanda L. ;
Le Pleux, Loic ;
Fortage, Jerome ;
Boschloo, Gerrit ;
Blart, Errol ;
Pellegrin, Yann ;
Odobel, Fabrice ;
Hagfeldt, Anders ;
Hammarstrom, Leif .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (24) :4402-4405
[10]   Excited-state properties of C60 fullerene derivatives [J].
Guldi, DM ;
Prato, M .
ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (10) :695-703
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