Synthesis and characterization of a new asymmetric dinucleating ligand and its dinuclear nickel(II) complex with (μ-I•2)2 phosphate ester bridge

被引：8

作者：

Ren, Yan-wei ^{[1
]}

Wu, Ai-zhi ^{[2
]}

Liu, Hai-yang ^{[1
]}

Jiang, Huang-feng ^{[1
]}

机构：

[1] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Peoples R China

[2] Guangzhou Univ Chinese Med, Sch Chinese Med, Guangzhou 510006, Peoples R China

来源：

TRANSITION METAL CHEMISTRY | 2010年 / 35卷 / 02期

关键词：

CRYSTAL-STRUCTURE; BINUCLEAR METALLOHYDROLASES; REDOX PROPERTIES; METAL-COMPLEXES; HYDROLYSIS; MODEL; UREASE; CLEAVAGE; PHOSPHODIESTER; MECHANISMS;

D O I：

10.1007/s11243-009-9313-x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new asymmetric phenol-based "end-off" dinucleating ligand HL was prepared using a modified methodology through a four-step synthesis. The ligand comprises two different coordination moieties, namely, a rigid 1,4-dimethyl-1,4,7-triazacyclononane unit and a more flexible N-(2-pyridyl)methyl-N-2-(2-pyridylethyl)amine unit. Its dinuclear Ni(II) complex containing two phosphate esters in a mu-I center dot(2) binding mode was synthesized and characterized by X-ray crystallography, in which each nickel atom is six-coordinate and adopts a slightly distorted octahedral coordination geometry.

引用

页码：191 / 195

页数：5

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