Photoluminescence, radioluminescence and thermoluminescence properties of Eu3+ doped cadmium tantalate phosphor

被引:16
作者
Ilhan, Mustafa [1 ]
Keskin, Ilker Cetin [2 ]
机构
[1] Marmara Univ, Dept Met & Mat Engn, Goztepe Campus, TR-34722 Istanbul, Turkey
[2] Celal Bayar Univ, Fac Arts & Sci, Dept Phys, Sehit Prof Dr Ilhan Varank Campus, TR-45140 Yunusemre, Manisa, Turkey
关键词
GOODNESS-OF-FIT; ENERGY-TRANSFER; SCINTILLATION PROPERTIES; CHARGE COMPENSATION; QUANTUM DOTS; THIN-FILMS; LUMINESCENCE; BEHAVIOR; CRYSTAL; DY3+;
D O I
10.1039/c8dt02395f
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
For investigate spectroscopic properties, Eu3+ doped columbite type CdTa2O6 phosphors were synthesized using the solid state reaction method. The synthesized ceramic phosphors were investigated by X-ray diffraction (XRD), scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS), photoluminescence (PL), radioluminescence (RL) and thermoluminescence (TL) analyses. CdTa2O6:Eu3+ phosphors exhibited emissions at 591.8 nm and 612.1 nm because of the characteristic band transitions of the Eu3+ ion. Phosphor emission increased with increasing Eu3+ ion dopant up to 1.5 mol%, and then decreased owing to concentration quenching. The decay times decreased with increasing Eu3+ dopant, while they were varied from 711 to 534 m. The scintillation emissions of Eu3+ doped samples from the UV to near-IR spectral region were monitored by RL measurements. The high RL emission may be attributed to the good scintillation property of phosphor. TL glow curves were monitored for different Eu3+ concentrations in the range of 50 degrees C to 400 degrees C at a heating rate of 2 degrees C s(-1), after being irradiated under short-wave UV light (254 nm).
引用
收藏
页码:13939 / 13948
页数:10
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