A High Loading and Recyclable Pentaerythritol Supported Imidazolidin-4-one Catalyst for Enantioselective Diels-Alder Reactions

被引：3
作者：
Du, Kaitao [1 ,2 ]
Lu, Cuifen [1 ,2 ]
Chen, Zuxing [1 ,2 ]
Nie, Junqi [1 ,2 ]
Yang, Guichun [1 ,2 ]
机构：
[1] Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organochem Mat, Wuhan 430062, Peoples R China
[2] Hubei Univ, Minist Educ, Key Lab Synth & Applicat Organ Funct Mol, Wuhan 430062, Peoples R China
来源：
CATALYSIS LETTERS | 2016年 / 146卷 / 06期
关键词：
High loading; Recyclable; Pentaerythritol; Imidazolidin-4-one; Diels-Alder reactions; CHIRAL IMIDAZOLIDIN-4-ONE; ORGANIC CATALYSIS; IONIC LIQUID; ASYMMETRIC ORGANOCATALYSIS; 1,3-DIPOLAR CYCLOADDITION; MACMILLAN CATALYST; STRATEGIES; IMMOBILIZATION; DENDRIMER; EFFICIENT;
D O I：
10.1007/s10562-016-1724-7
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The synthesis of high loading and recyclable pentaerythritol supported imidazolidin-4-one catalyst I and its application in enantioselective Diels-Alder reactions of cyclopentadiene and alpha,beta-unsaturated aldehydes with high performance were described. Especially noteworthy, the pentaerythritol supported imidazolidin-4-one with high loading capacity can be recovered by simple precipitation and filtration, and recycled for up to four runs without observing significant decrease in catalytic activity.
引用
收藏
页码：1107 / 1112
页数：6
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