Natural Deep Eutectic Solvents Enhanced Electro-Enzymatic Conversion of CO2 to Methanol

被引：7

作者：

Zhang, Zhibo ^{[1
]}

Wang, Hui ^{[2
]}

Nie, Yi ^{[3
,4
]}

Zhang, Xiangping ^{[4
]}

Ji, Xiaoyan ^{[1
]}

机构：

[1] Lulea Univ Technol, Div Energy Sci, Energy Engn, Lulea, Sweden

[2] Nanjing Tech Univ, State Key Lab Mat Oriented Chem Engn, Nanjing, Peoples R China

[3] Zhengzhou Inst Emerging Ind Technol, Zhengzhou, Peoples R China

[4] Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn,State Key Lab Multip, Beijing, Peoples R China

来源：

FRONTIERS IN CHEMISTRY | 2022年 / 10卷

关键词：

CO2; conversion; enzyme; NADESs; electrocatalysis; methanol; CARBON-DIOXIDE;

D O I：

10.3389/fchem.2022.894106

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electro-enzymatic conversion of CO2 offers a promising solution for CO2 utilization, while the conversion rate and efficiency were disappointing. To address the challenge, four kinds of natural deep eutectic solvents (NADES) with desirable biocompatibility were developed for the first time and used as the co-electrolyte in the electro-enzymatic conversion of CO2. As a result, the SerGly-based solution presents high CO2 solubility and high electrocatalytic activity, compared to the conventional buffer. By applying SerGly in the electro-enzymatic conversion of CO2, the yield of the product (methanol) is two times higher than that in the Tris-HCl buffer (0.22 mM) and 16 times higher than the control reaction.

引用

页数：8

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