Metal Catalysts for the Formation of Six-Membered N-Polyheterocycles

被引:59
作者
Kaur, Navjeet [1 ]
机构
[1] Banasthali Univ, Dept Chem, Banasthali 304022, Rajasthan, India
关键词
catalysis; heterocycles; nitrogen; MICROWAVE-ASSISTED SYNTHESIS; RING-CLOSING METATHESIS; ONE-POT SYNTHESIS; ACID TIC DERIVATIVES; MEDIATED ELECTROPHILIC CYCLIZATION; DIELS-ALDER REACTIONS; SOLID-PHASE SYNTHESIS; ALPHA-IMINO ACETATES; CP-ASTERISK-IR; ENANTIOSELECTIVE SYNTHESIS;
D O I
10.1080/15533174.2014.989620
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In recent decades, a large number of reports related to the synthesis of N-, O-, and S-containing heterocycles have appeared owing to a wide variety of their biological activity. The metal-catalyzed synthesis of heterocycles is becoming an important and highly rewarding protocol in organic synthesis. This review focuses on the use of metal as a catalyst for the synthesis of nitrogen containing six-membered polyheterocylces. It describes the formation of different types of heterocyclic rings using different metal catalysts.
引用
收藏
页码:983 / 1020
页数:38
相关论文
共 240 条
[1]   Rh-catalyzed sequential hydroarylation/hydrovinylation-heterocyclization of β-(2-aminophenyl)-α,β-ynones with organoboron derivatives:: A new approach to functionalized quinolines [J].
Abbiati, Giorgio ;
Arcadi, Antonio ;
Marinelli, Fabio ;
Rossi, Ellsabetta ;
Verdecchia, Mirella .
SYNLETT, 2006, (19) :3218-3224
[2]   Synthesis of pumiliotoxine C from molecular nitrogen as a nitrogen source [J].
Akashi, M ;
Sato, Y ;
Mori, M .
JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (23) :7873-7874
[3]   NOVEL SYNTHESIS OF INDOLES VIA PALLADIUM-CATALYZED REDUCTIVE N-HETEROCYCLIZATION OF ORTHO-NITROSTYRENE DERIVATIVES [J].
AKAZOME, M ;
KONDO, T ;
WATANABE, Y .
CHEMISTRY LETTERS, 1992, (05) :769-772
[4]   Enantioselective aza-Diels-Alder reaction catalyzed by a chiral Bronsted acid: Effect of the additive on the enantioselectivity [J].
Akiyama, T ;
Tamura, Y ;
Itoh, J ;
Morita, H ;
Fuchibe, K .
SYNLETT, 2006, (01) :141-143
[5]   An improved synthesis of methyl 1,3-Dihydro-2H-pyrrolo[3,4-b]quinoline-2-carboxylate [J].
Akue-Gedu, Rufine ;
Gautret, Philippe ;
Lelieur, Jean-Pierre ;
Rigo, Benoit .
SYNTHESIS-STUTTGART, 2007, 21 (21) :3319-3322
[6]   Aryl-aryl bond formation by transition-metal-catalyzed direct arylation [J].
Alberico, Dino ;
Scott, Mark E. ;
Lautens, Mark .
CHEMICAL REVIEWS, 2007, 107 (01) :174-238
[7]   Rh(I)-catalyzed coupling cyclization of N-aryl trifluoroacetimidoyl chlorides with alkynes:: One-pot synthesis of fluorinated quinolines [J].
Amii, H ;
Kishikawa, Y ;
Uneyama, K .
ORGANIC LETTERS, 2001, 3 (08) :1109-1112
[8]   Alternative synthetic methods through new developments in catalysis by gold [J].
Arcadi, Antonio .
CHEMICAL REVIEWS, 2008, 108 (08) :3266-3325
[9]   METAL-ASSISTED N-HETEROCYCLE SYNTHESIS .5. CONVERSION OF N-ALLYLANILINE PROMOTED BY RH(I) - SYNTHESIS AND MOLECULAR-STRUCTURE OF 2-ETHYL-1,2,3,4-TETRAHYDRO-3-METHYL-4-ANILINOQUINOLINE [J].
ARESTA, M ;
QUARANTA, E ;
TREGLIA, S ;
IBERS, JA .
ORGANOMETALLICS, 1988, 7 (03) :577-583
[10]   Synthesis of substituted 1,2-dihydroquinolines and quinolines using ene-ene metathesis and ene-enol ether metathesis [J].
Arisawa, M ;
Theeraladanon, C ;
Nishida, A ;
Nakagawa, M .
TETRAHEDRON LETTERS, 2001, 42 (45) :8029-8033