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DeNOx Abatement Modelling over Sonically Prepared Copper USY and ZSM5 Structured Catalysts
被引:15
|作者:
Jodlowski, Przemyslaw J.
[1
]
Kuterasinski, Lukasz
[2
]
Jedrzejczyk, Roman J.
[3
]
Chlebda, Damian
[4
]
Gancarczyk, Anna
[5
]
Basag, Sylwia
[4
]
Chmielarz, Lucjan
[4
]
机构:
[1] Cracow Univ Technol, Fac Chem Engn & Technol, Warszawska 24, PL-31155 Krakow, Poland
[2] Polish Acad Sci, Jerzy Haber Inst Catalysis & Surface Chem, Niezapominajek 8, PL-30239 Krakow, Poland
[3] Jagiellonian Univ, Malopolska Ctr Biotechnol, Gronostajowa 7A, PL-30387 Krakow, Poland
[4] Jagiellonian Univ, Fac Chem, Ingardena 3, PL-30060 Krakow, Poland
[5] Polish Acad Sci, Inst Chem Engn, Baltycka 5, PL-44100 Gliwice, Poland
来源:
关键词:
structured reactors;
deNO(x) selective catalytic reduction (SCR);
zeolites;
modelling;
HEAT-TRANSFER;
FLOW RESISTANCE;
WIRE GAUZES;
ULTRASONIC TREATMENT;
ACTIVATED CARBON;
ZEOLITE;
NOX;
REDUCTION;
AMMONIA;
NH3-SCR;
D O I:
10.3390/catal7070205
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
Metallic supports play an important role as structured reactor internals. Due to their specific properties including enhanced heat and mass transport, high mechanical resistivity and elimination of local hot-spots, they are commonly used in gas exhaust abatement from stationary and automotive industries. In this study, the performance of three structured supports with deposited Cu/USY (Ultrastabilised Y-zeolite) for deNO(x) abatement were modelled. Based on kinetic and flow resistance experimental results, the one-dimensional (1D) model of structured reactor was developed. The performance of the structured reactors was compared by the length of the reactor necessary to achieve an arbitrary 90% NOx conversion. The performed simulations showed that the sonochemically prepared copper USY and ZSM-5 zeolites deposited on metallic supports may be successfully used as catalysts for deNO(x) process.
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页数:14
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