Novel oxygen sensitive complexes for optical oxygen sensing

被引：41
作者：
Fernandez-Sanchez, J. F.
Roth, T.
Cannas, R.
Nazeeruddin, Md. K.
Spichiger, S.
Graetzel, M.
Spichiger-Keller, U. E.
机构：
[1] Univ Granada, Fac Sci, Dept Analyt Chem, E-18071 Granada, Spain
[2] ETHZ, Ctr Chem Sensors, Swiss Fed Inst Technol, CH-8005 Zurich, Switzerland
[3] Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, Inst Chem Sci & Engn, CH-1015 Lausanne, Switzerland
来源：
TALANTA | 2007年 / 71卷 / 01期
关键词：
optical sensor; luminescence; oxygen; ruthenium complex; iridium complex; sterilization;
D O I：
10.1016/j.talanta.2006.03.043
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Novel optical sensing films for oxygen based on highly luminescent iridium (111) and ruthenium (11) complexes have been developed. These demonstrate excellent long-term photostability (several months) when incorporated into polystyrene membranes. The influence of different plasticizers on the specific luminescence quantum yield, the Stern-Volmer constant, the reversibility and the response time were evaluated. Additionally the sensing films can be sterilized by chemical cleaning and gamma-ray irradiation. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：242 / 250
页数：9
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