Anisotropy in elastic properties of lithium sodium sulphate hexahydrate single crystal-An ultrasonic study

被引:2
作者
Varughese, George [1 ]
Kumar, A. Santhosh [2 ]
Philip, J. [3 ]
Louis, Godfrey [4 ]
机构
[1] Catholicate Coll, Dept Phys, Pathanamthitta 689648, India
[2] Mahatma Gandhi Univ, Sch Pure & Appl Biol, Kottayam 686560, Kerala, India
[3] Cochin Univ Sci & Technol, Sophisticated Test & Instrumentat Ctr, Kochi 682022, India
[4] Cochin Univ Sci & Technol, Dept Phys, Kochi 682022, India
关键词
Inorganic crystal; ultrasonics; elastic properties;
D O I
10.1007/s12034-009-0096-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The double sulfate family (ABSO(4)), Where A and B are alkali metal cations, is the object of great interest owing to the complexity and richness of its sequence of phase transition induced by temperature variation. A new sulfate salt characterized by the presence of water molecule in the unit cell with the chemical formula, Li2Na3(SO4)(2)center dot 6H(2)O (LSSW), was obtained. The ultrasonic velocity measurement was done with pulse echo overlap technique [PEO]. All the six second order elastic stiffness constants, C-11 = C-22, C-33, C-44 = C-55, C-12, C-14 and C-13 = C-23 are reported for the first time. The anisotropy in the elastic properties of the crystal are well explained by the pictorial representation of the polar plots of phase velocity, slowness, Young's modulus and linear compressibility in a-b and a-c planes.
引用
收藏
页码:621 / 626
页数:6
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