Synthesis, crystal structures, biological screening and electrochemical analysis of some salen-based transition metal complexes

被引：15
作者：
Tadavi, Samina K. [1 ]
Rajput, Jamatsing D. [1 ]
Bagul, Suresh D. [1 ]
Hosamani, Amar A. [2 ]
Sangshetti, Jaiprakash N. [3 ]
Bendre, Ratnamala S. [1 ]
机构：
[1] North Maharashtra Univ, Sch Chem Sci, Jalgaon 425001, Maharashtra, India
[2] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India
[3] YB Chavan Coll Pharm, Dr Rafiq Zakaria Campus, Aurangabad 431001, Maharashtra, India
来源：
RESEARCH ON CHEMICAL INTERMEDIATES | 2017年 / 43卷 / 08期
关键词：
N2O2; donor; Transition metal complexes; Cyclic voltammetry; ESR; SWITCH-ON DETECTION; COPPER(II) COMPLEXES; SPECTRAL CHARACTERIZATION; ANTIBACTERIAL ACTIVITIES; TETRADENTATE COMPLEXES; IRIDIUM(III) COMPLEX; CU(II) COMPLEXES; SCHIFF-BASES; 1ST EVIDENCE; NICKEL(II);
D O I：
10.1007/s11164-017-2917-4
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new series of transition metal complexes with (1) Mn(III), (2) Co(II), (3) Ni(II) and (4) Cu(II) have been synthesized by the reaction of [ 6,60'-((1E, 1'E)( propane-1,3-diylbis(azanylylidene)) bis(methanylylidene)) bis(5-isopropyl-2-methylphenol)] with suitable metal salts. The synthesized complexes have been characterized by elemental analysis and spectroscopic techniques. The results of single crystal structures show that the metal is bonded to the ligand through the phenolic oxygens and imino nitrogens. Synthesized complexes have been evaluated for antibacterial activity and antioxidant activity, which shows considerable results.
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收藏
页码：4863 / 4879
页数：17
相关论文
共 58 条
  • [11] 2-Q
  • [12] A highly selective and sensitive "Turn-On" fluorescence chemosensor for the Cu2+ ion in aqueous ethanolic medium and its application in live cell imaging
    Chatterjee, Nabanita
    Mahaling, Binapani
    Sivakumar, Sri
    Bharadwaj, Parimal K.
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2016, 330 : 110 - 116
  • [13] Nickel(II) and copper(II) complexes of tetradentate unsymmetrical Schiff base ligands: First evidence of positional isomerism in such system
    Chattopadhyay, S
    Ray, MS
    Chaudhuri, S
    Mukhopadhyay, G
    Bocelli, G
    Cantoni, D
    Ghosh, A
    [J]. INORGANICA CHIMICA ACTA, 2006, 359 (05) : 1367 - 1375
  • [14] Ruthenium(II) complexes containing bidentate Schiff bases and their antifungal activity
    Dharmaraj, N
    Viswanathamurthi, P
    Natarajan, K
    [J]. TRANSITION METAL CHEMISTRY, 2001, 26 (1-2) : 105 - 109
  • [15] Synthesis, characterization and electrochemical behaviour of some copper(II) complexes with linear and tripodal tetradentate ligands derived from Schiff bases
    DjebbarSid, S
    BenaliBaitich, O
    Deloume, JP
    [J]. POLYHEDRON, 1997, 16 (13) : 2175 - 2182
  • [16] OLEX2: a complete structure solution, refinement and analysis program
    Dolomanov, Oleg V.
    Bourhis, Luc J.
    Gildea, Richard J.
    Howard, Judith A. K.
    Puschmann, Horst
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2009, 42 : 339 - 341
  • [17] Dutta R. L., 1992, ELEMENTS MAGNETOCHEM
  • [18] Farrugia L. J., 2002, J APPL CRYSTALLOGR, V30, P565
  • [19] Greenwood D., 1992, MED MICROBIOLOGY, V1
  • [20] Spectral regression and correlation coefficients of some benzaldimines and salicylaldimines in different solvents
    Hammud, HH
    Ghannoum, A
    Masoud, MS
    [J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2006, 63 (02) : 255 - 265
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