Synthesis, crystal structures, biological screening and electrochemical analysis of some salen-based transition metal complexes

被引：15

作者：

Tadavi, Samina K. ^{[1
]}

Rajput, Jamatsing D. ^{[1
]}

Bagul, Suresh D. ^{[1
]}

Hosamani, Amar A. ^{[2
]}

Sangshetti, Jaiprakash N. ^{[3
]}

Bendre, Ratnamala S. ^{[1
]}

机构：

[1] North Maharashtra Univ, Sch Chem Sci, Jalgaon 425001, Maharashtra, India

[2] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India

[3] YB Chavan Coll Pharm, Dr Rafiq Zakaria Campus, Aurangabad 431001, Maharashtra, India

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2017年 / 43卷 / 08期

关键词：

N2O2; donor; Transition metal complexes; Cyclic voltammetry; ESR; SWITCH-ON DETECTION; COPPER(II) COMPLEXES; SPECTRAL CHARACTERIZATION; ANTIBACTERIAL ACTIVITIES; TETRADENTATE COMPLEXES; IRIDIUM(III) COMPLEX; CU(II) COMPLEXES; SCHIFF-BASES; 1ST EVIDENCE; NICKEL(II);

D O I：

10.1007/s11164-017-2917-4

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new series of transition metal complexes with (1) Mn(III), (2) Co(II), (3) Ni(II) and (4) Cu(II) have been synthesized by the reaction of [ 6,60'-((1E, 1'E)( propane-1,3-diylbis(azanylylidene)) bis(methanylylidene)) bis(5-isopropyl-2-methylphenol)] with suitable metal salts. The synthesized complexes have been characterized by elemental analysis and spectroscopic techniques. The results of single crystal structures show that the metal is bonded to the ligand through the phenolic oxygens and imino nitrogens. Synthesized complexes have been evaluated for antibacterial activity and antioxidant activity, which shows considerable results.

引用

页码：4863 / 4879

页数：17

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