Heteroelements, useful tools for the study of potential surfaces: the example of the phosphorus/boron combination and 1,3-diradicals

被引：0
作者：
Bourissou, Didier [1 ]
机构：
[1] Univ Toulouse 3, UMR 5069, Lab Heterochim Fondamentale & Appl, Equipe Ligands Bifonct & Polymeres Biodegradables, F-31062 Toulouse 9, France
来源：
ACTUALITE CHIMIQUE | 2007年
关键词：
highly reactive species; stabilisation; heteroelements; free radicals; diradicals;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Heteroelements, useful tools for the study of potential surfaces: the example of the phosphorus/ boron combination and 1,3-diradicals The stabilisation of transient species is not only a stimulating challenge for synthetic chemists but also a valuable source of informations. The various approaches used to characterize, or even isolate, such species are presented for carbocations. The example of 1,3-diradicals is then detailed, highlighting the interest of heteroelements, and more particularly of the phosphorus/boron combination.
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页码：21 / 26
页数：6
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