Synthesis of Mono and Bis[60]fullerene-Based Dicationic Peptoids

被引：11

作者：

Jennepalli, Sreenu ^{[1
]}

Hammer, Katherine A. ^{[2
]}

Riley, Thomas V. ^{[2
]}

Pyne, Stephen G. ^{[1
]}

Keller, Paul A. ^{[1
]}

机构：

[1] Univ Wollongong, Sch Chem, Wollongong, NSW 2522, Australia

[2] Univ Western Australia, Sch Pathol & Lab Med, Crawley, WA 6009, Australia

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 2015卷 / 01期

基金：

英国医学研究理事会;

关键词：

Medicinal chemistry; Antibiotics; Amino acids; Peptides; Fullerenes; Template synthesis; AMINO-ACIDS; STAPHYLOCOCCUS-AUREUS; GENE DELIVERY; ANTIBACTERIAL; FULLERENE; VANCOMYCIN; PEPTIDES; ESTERS; DRUGS;

D O I：

10.1002/ejoc.201403046

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Increasing numbers of biological applications of fullerenyl amino acids and their derivatives encouraged us to synthesise [60]fullerenyldihydropyrrole peptides, prepared from the coupling of mono- and bis[60]fullerenyldihydropyrrolecarboxylic acids 4, 5 and 41 with presynthesised peptides 13, 16, 24, 28, 29 and 46. The resulting hydrophobic scaffolded di- and tetra-cationic derivatives were tested against Staphylococcus aureus NCTC 6571 and Escherichia coli NCTC 10418. The synthesis, characterisation and biological results are discussed in this paper.

引用

页码：195 / 201

页数：7

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