Phenolphthalein Conjugated Schiff Base as a Dual Emissive Fluorogenic Probe for the Recognition Aluminum (III) and Zinc (II) Ions

被引：12

作者：

Aydin, Duygu ^{[1
]}

Alici, Meliha Kutluca ^{[2
]}

机构：

[1] Karamanoglu Mehmetbey Univ, Kamil Ozdag Sci Fac, Dept Chem, TR-70100 Karaman, Turkey

[2] Nigde Omer Halisdemir Univ, Dept Lab & Vet Hlth, TR-51700 Nigde, Turkey

来源：

JOURNAL OF FLUORESCENCE | 2021年 / 31卷 / 03期

关键词：

Isoniazid; Fluorogenic sensor; Aluminum; Zinc; ESIPT;

D O I：

10.1007/s10895-021-02704-5

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

In this study, a new phenolphthalein derivative, FFIZNA, has been planned and successfully prepared in an uncomplicated way. The probe FFIZNA could selectively monitor Al3+ and Zn2+ among other relevant cations with diverse colors through a turn-on emission response in EtOH:HEPES (9/1;v/v) media owing to the chelation enhanced fluorescence (CHEF), prevention of ESIPT, -C=N- isomerization and PET of the probe FFIZNA. The interactions of Al3+ and Zn2+ with the probe FFIZNA were confirmed by emission spectroscopy, Job's plot and H-1-NMR titration substantiated 1:2 reaction stoichiometry between FFIZNA and Al3+ and Zn2+. The time-response study displayed that the emission of FFIZNA with Al3+ and Zn2+, rapidly boosted and reached the stable value in less than 3.0 and 4.0 min, respectively. Therefore, the FFIZNA has successfully been utilized to the dual recognition of Al3+ and Zn2+ in solutions.

引用

页码：797 / 805

页数：9

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