A Nanoscopic 3D Polyferrocenyl Assembly: The Triacontakaihexa(ferrocenylmethylthiolate) [Ag48(μ4-S)6(μ2/3-SCH2Fc)36]

被引：43

作者：

Ahmar, Siawash ^{[1
]}

MacDonald, Daniel G. ^{[1
]}

Vijayaratnam, Niranjan ^{[1
]}

Battista, Taylor L. ^{[1
]}

Workentin, Mark S. ^{[1
]}

Corrigan, John F. ^{[1
]}

机构：

[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 26期

基金：

加拿大自然科学与工程研究理事会;

关键词：

clusters compounds; cyclovoltammetry; ferrocenyl ligands; nanomaterials; silver; MOLECULAR RECOGNITION; NANOPARTICLES; DENDRIMERS; CLUSTERS;

D O I：

10.1002/anie.201000686

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) The molecular nanocluster [Ag48(μ 4-S)6 (μ3-SCH2Fc)36] (1) (see picture; Ag blue, S yellow, Fe orange, C gray; Fc = ferrocenyl) has been prepared in good yield and characterized by single-crystal X-ray diffraction. The 36 ferrocenylmethylthiolate ligands envelop the Ag-S core. Cyclic voltammetry of 1 displays one reversible oxidation wave. © 2010 Wiley-VCH Verlag GmbH &. Co. KGaA, Weinheim.

引用

页码：4422 / 4424

页数：3

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