Forensic examination of thermal papers using Video Spectral Comparator (VSC) and ATR-FTIR spectroscopy coupled with chemometrics: Non-destructive approach

被引:4
作者
Tomar, Anjali [1 ]
Gupta, Reeta R. [2 ]
Kaur, Amanpreet [1 ]
Semwal, J. K. [3 ]
Kumar, Sanjeev [3 ]
Mehta, S. K. [4 ]
Sharma, Shweta [1 ]
机构
[1] Panjab Univ, Inst Forens Sci & Criminol, Chandigarh 160014, India
[2] CBI, Cent Forens Sci Lab, New Delhi 110003, India
[3] MHA, LNJN Natl Inst Criminol & Forens Sci, New Delhi 110085, India
[4] Panjab Univ, Dept Chem, Chandigarh 160014, India
关键词
Forensic; Thermal paper; ATR-FTIR; Video Spectral Comparator; Chemometrics; IR;
D O I
10.1016/j.saa.2021.119982
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Thermal papers are replacing the conventional form of printing and are being extensively used across the globe. This study encompasses a non-destructive approach to examine thermal papers by using ATR-FTIR spectroscopy and Video Spectral Comparator (VSC), where the former technique helps in characterizing and discriminating different samples and the latter helps in deciphering the faded prints on thermal paper. The qualitative analysis of the spectroscopic data based on peak to peak comparison and quanti-tative analysis using chemometrics has been done to obtain high discriminating power. Multivariate analysis using HCA gave a discriminating power of 83.82% and PCA showed a variance of 95.64%. The strength of the study is portrayed through the decipherment of artificially and naturally faded thermal papers using VSC and analyzing the effect of different storing conditions on their rate of fading. (c) 2021 Elsevier B.V. All rights reserved.
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页数:10
相关论文
共 28 条
[1]  
Brereton R.G., 2003, Chemometrics: Data Analysis for the Laboratory and Chemical Plant
[2]   Principal component analysis [J].
Bro, Rasmus ;
Smilde, Age K. .
ANALYTICAL METHODS, 2014, 6 (09) :2812-2831
[3]   Natural decay of archaeological oak wood versus artificial degradation processes-An FT-IR spectroscopy and X-ray diffraction study [J].
Broda, Magdalena ;
Popescu, Carmen-Mihaela .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2019, 209 :280-287
[4]  
Brown S.D, 2010, APPL SPECTROSC, V64
[5]   A Sensitive Non-destructive Method for Detection of Document Frauds using Thermal Ink [J].
Chayal, Vivekkumar Mangilal ;
Handa, Deepak R. ;
Singh, Jeet ;
Menon, Shobhana K. .
AUSTRALIAN JOURNAL OF FORENSIC SCIENCES, 2016, 48 (05) :601-612
[6]  
Coating N.T, GUIDE THERMAL PAPER
[7]   WHEN IS A CORRELATION MATRIX APPROPRIATE FOR FACTOR-ANALYSIS - DECISION RULES [J].
DZIUBAN, CD ;
SHIRKEY, EC .
PSYCHOLOGICAL BULLETIN, 1974, 81 (06) :358-361
[8]   Chemical and mineral characterization of Romanian book paper materials (XVII-XIXth century) [J].
Fierascu, Irina ;
Fierascu, Radu Claudiu ;
Stirban, Alexandru ;
Panaitescu, Denis Mihaela ;
Nicolae, Cristian Andi ;
Raditoiu, Valentin ;
Zgarciu, Maria-Similia ;
Leahu, Ariana Codruta .
MICROCHEMICAL JOURNAL, 2020, 152
[9]   Clustering with dendrograms on interpretation variables [J].
Forina, A ;
Armanino, C ;
Raggio, V .
ANALYTICA CHIMICA ACTA, 2002, 454 (01) :13-19
[10]   Forensic discrimination of black laser prints by a combination of chemometric methods and μ-ATR-FTIR spectroscopy [J].
Gal, Lukas ;
Oravec, Michal ;
Kissova, Michaela ;
Gemeiner, Pavol ;
Ceppan, Michal .
CHEMICAL PAPERS, 2020, 74 (10) :3269-3277