Lithium Ion Insertion in Titania Nanotube Powders Synthesized by Rapid Breakdown Anodization

被引:14
作者
Park, Sang-Jun [1 ]
Paek, Yeong-Kyeun [1 ]
Lee, Hyukjae [1 ]
Kim, Young-Jun [2 ]
机构
[1] Andong Natl Univ, Ctr Green Mat Technol, Andong 760745, Gyungbuk, South Korea
[2] Korea Elect Technol Inst, Adv Battery Res Ctr, Songnam 463816, Gyeonggi, South Korea
关键词
INTERCALATION; ARRAYS;
D O I
10.1149/1.3418617
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Titania nanotubes are synthesized via rapid breakdown anodization and their lithium insertion properties are investigated. Anodization of Ti thin foil in perchloric acid produces TiO2 nanotube powders in less than 30 min. Annealing of the synthesized TiO2 nanotubes results in anatase and rutile phases from the originally amorphous phase. The lithium insertion performance of the TiO2 nanotube is strongly dependent on the annealing condition. Due to its simplicity and short time for synthesis, rapid breakdown anodization can be a viable option to produce TiO2 nanotubes for lithium ion battery applications. (C) 2010 The Electrochemical Society. [DOI: 10.1149/1.3418617] All rights reserved.
引用
收藏
页码:A85 / A87
页数:3
相关论文
共 20 条
[1]   Lithium-ion intercalation into TiO2-B nanowires [J].
Armstrong, AR ;
Armstrong, G ;
Canales, J ;
García, R ;
Bruce, PG .
ADVANCED MATERIALS, 2005, 17 (07) :862-+
[2]   A Novel Method for Synthesis of Titania Nanotube Powders using Rapid Breakdown Anodization [J].
Fahim, Narges F. ;
Sekino, Tohru .
CHEMISTRY OF MATERIALS, 2009, 21 (09) :1967-1979
[3]   Electrochemical Growth of Vertically-Oriented High Aspect Ratio Titania Nanotubes by Rabid Anodization in Fluoride-Free Media [J].
Fahim, Narges Fathy ;
Sekino, Tohru ;
Morks, Magdi Farouk ;
Kusunose, Takafumi .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2009, 9 (03) :1803-1818
[4]   Semiconductor nanotube formation by a two-step template process [J].
Hoyer, P .
ADVANCED MATERIALS, 1996, 8 (10) :857-&
[5]   TiO2@Sn core-shell nanotubes for fast and high density Li-ion storage material [J].
Kim, Hyesun ;
Kim, Min Gyu ;
Shin, Tae Joo ;
Shin, Hyun-Jun ;
Cho, Jaephil .
ELECTROCHEMISTRY COMMUNICATIONS, 2008, 10 (11) :1669-1672
[6]   Conformal Sn Coated TiO2 Nanotube Arrays and Its Electrochemical Performance for High Rate Lithium-Ion Batteries [J].
Kim, Hyun Sik ;
Kang, Soon Hyung ;
Chung, Young Hoon ;
Sung, Yung-Eun .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2010, 13 (02) :A15-A18
[7]   Preparation and novel lithium intercalation properties of titanium oxide nanotubes [J].
Li, JR ;
Tang, ZL ;
Zhang, ZT .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2005, 8 (06) :A316-A319
[8]   TiO2 nanotube arrays annealed in N2 for efficient lithium-ion intercalation [J].
Liu, Dawei ;
Xiao, Peng ;
Zhang, Yunhuai ;
Garcia, Betzaida B. ;
Zhang, Qifeng ;
Guo, Qing ;
Champion, Richard ;
Cao, Guozhong .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (30) :11175-11180
[9]   TiO2 nanotube arrays annealed in CO exhibiting high performance for lithium ion intercalation [J].
Liu, Dawei ;
Zhang, Yunhuai ;
Xiao, Peng ;
Garcia, Betzaida Batalla ;
Zhang, Qifeng ;
Zhou, Xiaoyuan ;
Jeong, Yoon-Ha ;
Cao, Guozhong .
ELECTROCHIMICA ACTA, 2009, 54 (27) :6816-6820
[10]   Smooth anodic TiO2 nanotubes [J].
Macak, JM ;
Tsuchiya, H ;
Taveira, L ;
Aldabergerova, S ;
Schmuki, P .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (45) :7463-7465