Electron-Catalyzed Cross-Coupling of Arylboron Compounds with Aryl Iodides

被引：14
|
作者：
Okura, Keisho [1 ]
Teranishi, Tsuyoshi [2 ]
Yoshida, Yuto [1 ]
Shirakawa, Eiji [2 ]
机构：
[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan
[2] Kwansei Gakuin Univ, Sch Sci & Technol, Dept Appl Chem Environm, Sanda, Hyogo 6691337, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2018年 / 57卷 / 24期
关键词：
arylboron compounds; biaryl compounds; cross-coupling; electron catalysis; radical reactions; METAL-FREE; ZINC TRANSMETALATION; GRIGNARD-REAGENTS; ALKENYL HALIDES; BORYLATION; ACIDS; HALOARENES; PALLADIUM; BORON; CARBONATE;
D O I：
10.1002/anie.201802813
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Arylboroxines in combination with zinc chloride and potassium tert-butoxide were found to undergo the electron-catalyzed cross-coupling with aryl iodides to give the corresponding biaryls without the aid of transition-metal catalysis.
引用
收藏
页码：7186 / 7190
页数：5
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