Reaction of imines with N-iodosuccinimide (NIS):: unexpected formation of stable 1:1 complexes

被引：43

作者：

Castellote, Isabel

Moron, Maria

Burgos, Carolina ^{[1
]}

Alvarez-Builla, Julio

Martin, Avelino

Gomez-Sal, Pilar

Vaquero, Juan J.

机构：

[1] Univ Alcala de Henares, Dept Quim Organ, Madrid 28871, Spain

[2] Univ Alcala de Henares, Dept Quim Inorgan, Madrid 28871, Spain

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 12期

关键词：

D O I：

10.1039/b615183c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Imines react with N-iodosuccinimide (NIS) to afford unexpected 1 : 1 complexes and the structure of one of these was determined by single-crystal X-ray diffraction; the reaction seems to be very general for substituted cyclic imines with solid stable complexes obtained in high yields; this is the first reported example of a halogen bonding interaction involving the C = N bond and NIS.

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页码：1281 / 1283

页数：3

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