A stable alkyl hydride of a first row transition metal

被引：55

作者：

MacAdams, LA ^{[1
]}

Buffone, GP ^{[1
]}

Incarvito, CD ^{[1
]}

Golen, JA ^{[1
]}

Rheingold, AL ^{[1
]}

Theopold, KH ^{[1
]}

机构：

[1] Univ Delaware, Ctr Catalyt Sci & Technol, Dept Chem & Biochem, Newark, DE 19716 USA

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 10期

关键词：

D O I：

10.1039/b301943h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogenolysis of a Cr(III) dialkyl precursor produced a binuclear chromium complex with a bridging hydride and a bridging alkyl; this structurally characterized organometallic compound is thermally very stable and does not undergo the expected reductive elimination of alkane.

引用

页码：1164 / 1165

页数：2

共 20 条

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