Ferrocenium salt induced ring expansion of a 2H-azaphosphirene complex:: Synthesis of the first Δ3-1,4,2-oxazaphospholene complexes

被引：15

作者：

Streubel, R ^{[1
]}

Neumann, C ^{[1
]}

Jones, PG ^{[1
]}

机构：

[1] Tech Univ Braunschweig, Inst Anorgan & Analyt Chem, D-38023 Braunschweig, Germany

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 15期

关键词：

D O I：

10.1039/b004795n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Regioselective ring expansion of the 2H-azaphosphirene tungsten complex 1 in CH2Cl2 is performed using sub-stoichiometric amounts of ferrocenium hexafluorophosphate and benzalaldehyde or cyclohexanone, thus yielding Delta(3)-1,4,2-oxazaphospholene complexes 2a,c; the molecular structure of complex 2c was established by a single crystal X-ray diffraction study.

引用

页码：2495 / 2496

页数：2

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