Bioinspired, high-stability, nonaqueous redox flow battery electrolytes

被引:22
|
作者
Huang, Haobo [1 ]
Howland, Rachael [1 ]
Agar, Ertan [2 ]
Nourani, Mahnaz [2 ]
Golen, James A. [1 ]
Cappillino, Patrick J. [1 ]
机构
[1] Univ Massachusetts Dartmouth, Dept Chem & Biochem, N Dartmouth, MA 02747 USA
[2] Univ Massachusetts Lowell, Dept Mech Engn, Lowell, MA 01854 USA
基金
美国国家科学基金会;
关键词
VANADIUM NATURAL PRODUCT; AMAVADIN; COMPLEXES; DENSITY; MODEL; COORDINATION; CATHOLYTE; COMPOUND; EXAMPLE; STORAGE;
D O I
10.1039/c7ta00365j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Using natural selection as a toolkit we have elucidated an active material for nonaqueous redox flow batteries (NRFB) that is stable to deep cycling, both under static cell conditions and in an operating flow battery, even in the presence of water. The compound is an analogue of molecules biosynthesized by Amanita mushrooms and was chosen as a molecular scaffold for a new family of NRFB due to its redox reversibility, ease of synthesis and extraordinary stability.
引用
收藏
页码:11586 / 11591
页数:6
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