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High-efficiency synergistic conversion of CO2 to methanol using Fe2O3 nanotubes modified with double-layer Cu2O spheres
被引:65
作者:
Li, Peiqiang
[1
]
Jing, Hua
[1
]
Xu, Jinfeng
[1
]
Wu, Chenxiao
[1
]
Peng, Hui
[1
]
Lu, Jing
[1
]
Lu, Fusui
[1
]
机构:
[1] Shandong Agr Univ, Dept Chem, Tai An 271018, Shandong, Peoples R China
来源:
基金:
中国国家自然科学基金;
关键词:
ELECTROCHEMICAL REDUCTION;
CARBON-DIOXIDE;
PHOTOELECTROCHEMICAL REDUCTION;
COPPER ELECTRODE;
HEMATITE;
NANORODS;
CATALYST;
ARRAYS;
D O I:
10.1039/c4nr02902j
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Cuprous oxide/hematite nanotubes (Cu2O/Fe2O3NTs) were prepared by a potentiostatic electrodeposited method, in which different structured Cu2O materials were modified onto Fe2O3 NTs surface. Among them, the material with double-layer Cu2O spheres (Cu2O/Fe2O3 NTs-30) showed excellent photoelectrocatalytic (PEC) properties with a suitable energy band gap (1.96 eV) and a smaller overpotential (0.18 V). Furthermore, Cu2O/Fe2O3 NTs-30 showed two types of synergisms in the PEC reduction of CO2: (i) between electrocatalysis and photocatalysis and (ii) between Cu2O and Fe2O3NTs. The faradaic efficiency and methanol yield reached 93% and 4.94 mmol L-1 cm(-2) after 6 h, respectively.
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页码:11380 / 11386
页数:7
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