Role of B2O3 and CaO in Al2O3 matrix composite: In-situ phases, density, hardness and wear resistance

被引:13
作者
Kasar, Ashish K. [1 ]
Watson, Kevin P. [1 ]
D'Souza, Brian [1 ]
Menezes, Pradeep L. [1 ]
机构
[1] Univ Nevada, Mech Engn, Reno, NV 89557 USA
基金
美国国家航空航天局;
关键词
Alumina; Aluminum borate; Friction; Wear; ALUMINUM BORATE WHISKER; TRIBOLOGICAL PROPERTIES; ELECTRONIC POLARIZABILITY; MECHANICAL-PROPERTIES; OPTICAL BASICITY; FABRICATION; MICROSTRUCTURE; LUBRICATION; CERAMICS; ENERGY;
D O I
10.1016/j.triboint.2022.107588
中图分类号
TH [机械、仪表工业];
学科分类号
0802 ;
摘要
A novel set of Al2O3-B2O3-CaO composites were manufactured using a cold press-sintering. The B2O3 content in the composites was varied from 5 to 20 wt% and 2 wt% CaO was added to the composites. Dry sliding tests were conducted against an alumina ball at 10-95% relative humidity. The presence of the in-situ formed aluminum borate in the composite enhanced the micro-hardness and wear resistance, whereas the humidity-sensitive alumina phase reduced friction. Furthermore, addition of CaO improved the relative density upto similar to 92% which also led to significant improvement in hardness and wear resistance. However, the friction was negatively affected. The mechanism for enhanced wear resistance is demonstrated by considering the crystal-chemical approach and polarization theory for the double oxide systems.
引用
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页数:14
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