Preparation of LiNi1/3Mn1/3Co1/3O2/Li3PS4 cathode composite particles using a new liquid-phase process and application to all-solid-state lithium batteries

被引：10
作者：
Matsuda, Reiko [1 ]
Hirahara, Eito [1 ]
Nguyen Huu Huy Phuc [1 ]
Muto, Hiroyuki [2 ]
Tsukasaki, Hirofumi [3 ]
Mori, Shigeo [3 ]
Matsuda, Atsunori [1 ]
机构：
[1] Toyohashi Univ Technol, Grad Sch Engn, Dept Elect & Elect Info Engn, 1-1 Hibarigaoka,Tempaku Cho, Toyohashi, Aichi 4418580, Japan
[2] Toyohashi Univ Technol, Inst Liberal Arts & Sci, 1-1 Hibarigaoka,Tempaku Cho, Toyohashi, Aichi 4418580, Japan
[3] Osaka Prefecture Univ, Grad Sch Engn, Dept Mat Sci, Naka Ku, 1-1 Gakuen, Sakai, Osaka 5998531, Japan
来源：
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN | 2018年 / 126卷 / 10期
基金：
日本科学技术振兴机构;
关键词：
All-solid-state battery; Composite; Lithium; Li3PS4; LICOO2; ELECTRODE; LI6PS5CL;
D O I：
10.2109/jcersj2.18080
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The sulfide based electrolyte Li3PS4 was directly produced on the cathode active materials LiNi1/3Mn1/3Co1/3O2 (NMC) using the SEED method which was a new liquid-phase process developed by applying liquid-phase shaking method. The generation of PS43- unit in the SEED process was confirmed by in-situ Raman spectroscopy measurement. The generation of beta-Li3PS4 on NMC was shown using X-ray elemental mapping, transmission electron microscope observation and electron diffraction analysis. An all-solid-state cell composed of [90NMC center dot 10Li(3)PS(4) by SEED composite vertical bar Li3PS4 vertical bar In] was fabricated. It showed promising charge-discharge cycle performance, which could be ascribed to good retention of electrochemical contact at the interface between NMC and the electrolyte during the cycling. (C) 2018 The Ceramic Society of Japan. All rights reserved.
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页码：826 / 831
页数：6
相关论文
共 14 条
[1]   Interface Stability of Argyrodite Li6PS5Cl toward LiCoO2, LiNi1/3Co1/3Mn1/3O2, and LiMn2O4 in Bulk All-Solid-State Batteries [J].
Auvergniot, Jeremie ;
Cassel, Alice ;
Ledeuil, Jean-Bernard ;
Viallet, Virginie ;
Seznec, Vincent ;
Dedryvere, Remi .
CHEMISTRY OF MATERIALS, 2017, 29 (09) :3883-3890
[2]   Synthesis, Structural Characterization, and Lithium Ion Conductivity of the Lithium Thiophosphate Li2P2S6 [J].
Dietrich, Christian ;
Weber, Dominik A. ;
Culver, Sean ;
Senyshyn, Anatoliy ;
Sedlmaier, Stefan J. ;
Indris, Sylvio ;
Janek, Juergen ;
Zeier, Wolfgang G. .
INORGANIC CHEMISTRY, 2017, 56 (11) :6681-6687
[3]   Conformational Preferences of Ethyl Propionate Molecule: Raman, Temperature Dependent FTIR Spectroscopic Study Aided by ab Initio Quantum Chemical and Car-Parrinello Molecular Dynamics Simulation Studies [J].
Dutta, Bipan ;
Tanaka, Takeyuki ;
Banerjee, Arup ;
Chowdhury, Joydeep .
JOURNAL OF PHYSICAL CHEMISTRY A, 2013, 117 (23) :4838-4850
[4]  
Hayashi A, 2001, J AM CERAM SOC, V84, P477, DOI 10.1111/j.1151-2916.2001.tb00685.x
[5]  
Kamaya N, 2011, NAT MATER, V10, P682, DOI [10.1038/nmat3066, 10.1038/NMAT3066]
[6]   Synthesis of plate-like Li3PS4 solid electrolyte via liquid-phase shaking for all-solid-state lithium batteries [J].
Nguyen Huu Huy Phuc ;
Morikawa, Kei ;
Mitsuhiro, Totani ;
Muto, Hiroyuki ;
Matsuda, Atsunori .
IONICS, 2017, 23 (08) :2061-2067
[7]  
Phuc N.H.H., 2018, ADV CHEM RES, V42
[8]   Chemical synthesis of Li3PS4 precursor suspension by liquid-phase shaking [J].
Phuc, Nguyen Huu Huy ;
Morikawa, Kei ;
Totani, Mitsuhiro ;
Muto, Hiroyuki ;
Matsuda, Atsunori .
SOLID STATE IONICS, 2016, 285 :2-5
[9]   Sulfide Solid Electrolyte with Favorable Mechanical Property for All-Solid-State Lithium Battery [J].
Sakuda, Atsushi ;
Hayashi, Akitoshi ;
Tatsumisago, Masahiro .
SCIENTIFIC REPORTS, 2013, 3
[10]   LiCoO2 Electrode Particles Coated with Li2S-P2S5 Solid Electrolyte for All-Solid-State Batteries [J].
Sakuda, Atsushi ;
Hayashi, Akitoshi ;
Ohtomo, Takamasa ;
Hama, Shigenori ;
Tatsumisago, Masahiro .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2010, 13 (06) :A73-A75
12