Photo-Electrochemical C-H Bond Activation of Cyclohexane Using a WO3 Photoanode and Visible Light

被引：115
作者：
Tateno, Hiroyuki [1 ]
Iguchi, Shoji [1 ]
Miseki, Yugo [1 ]
Sayama, Kazuhiro [1 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Adv Funct Mat Team, Res Ctr Photovolta RCPV, Cent 5,1-1-1 Higashi, Tsukuba, Ibaraki 3058565, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2018年 / 57卷 / 35期
关键词：
alkanes; C-H activation; electrochemistry; oxidation; photocatalysis; HETEROGENEOUS PHOTOCATALYTIC OXIDATION; TITANIUM-DIOXIDE; SELECTIVE PHOTOOXIDATION; TIO2; HYDROCARBONS; IRRADIATION; WATER; BIVO4/WO3; CATALYST; ANATASE;
D O I：
10.1002/anie.201805079
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The photo-electrochemical C-H bond activation of cyclohexane to produce cyclohexanol and cyclohexanone (KA oil) with high partial oxidation selectivity (99%) and high current utilization ratio (76%) was achieved in air at room temperature at atmospheric pressure. The production rate of KA oil was accelerated by applying a bias. The incident photon to current efficiencies at 365 and 420nm were 57% and 24%, respectively.
引用
收藏
页码：11238 / 11241
页数：4
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