A Stable 1,2-Disilacyclohexene and Its 14-Electron Palladium(0) Complex

被引：32

作者：

Abe, Takashi ^{[1
]}

Iwamoto, Takeaki ^{[1
]}

Kira, Mitsuo ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 14期

关键词：

DISILYNE RSISIR R; SI-SI; SILICON-COMPOUNDS; REACTIVITY; CHEMISTRY; BONDS; MOLYBDENUM; COMPOUND; PLATINUM; ELEMENTS;

D O I：

10.1021/ja101654b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel stable cyclic disilene, 1,2-diphenyl-3,3,6,6-tetrakis(trimethylsilyl)-1,2-disilacyclohexene (1), was synthesized via the reaction of the corresponding 1,4-dilithiobutane with phenylchlorosilane. This new strategy would be applicable to the synthesis of stable cyclic disilenes having rather small residual substituents on unsaturated silicon atoms. A stable tricoordinate Y-shaped disilene palladium complex, 2, that was synthesized by the reaction of 1 with bis(tricyclohexylphosphine)palladium was found to have the strongest pi-complex character among known disilene palladium complexes.

引用

页码：5008 / +

页数：3

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