Synthesis of Unnatural Arundines Using a Magnetically Reusable Copper Ferrite Catalyst

被引：13

作者：

Ha, Pha T. ^{[1
]}

Nguyen, Oanh T. K. ^{[1
]}

Huynh, Khoa D. ^{[1
]}

Nguyen, Tung T. ^{[1
]}

Phan, Nam T. S. ^{[1
]}

机构：

[1] HCMC Univ Technol, VNU HCM, Fac Chem Engn, 268 Ly Thuong Kiet,Dist 10, Ho Chi Minh City, Vietnam

来源：

SYNLETT | 2018年 / 29卷 / 15期

关键词：

copper ferrite; C-H functionalization; indoles; Arundine; dimerization; C-H BONDS; LIGAND-FREE CONDITIONS; ONE-POT SYNTHESIS; CUFE2O4; NANOPARTICLES; METHYLENATING REAGENT; ARYLATION; INDOLES; CUO; BIS; FUNCTIONALIZATION;

D O I：

10.1055/s-0037-1610227

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report a method for copper ferrite-catalyzed coupling of indoles and N,N-dimethylacetamide (DMA) to afford Arundine derivatives. Halogen, methoxy, boronate ester, and trimethylsilyl functionalities are compatible with reaction conditions. Unprotected or sterically hindered indoles are also competent substrates. Indoles containing competitively reactive pyrazoles deliver the desired products in reasonable yields. The copper ferrite is easily recovered and reused, up to nine times without a significant yield loss.

引用

页码：2031 / 2034

页数：4

共 50 条

[21] Cobalt ferrite nanoparticles (CoFe2O4 MNPs) as catalyst and support: magnetically recoverable nanocatalysts in organic synthesis
Kazemi, Mosstafa
Ghobadi, Massoud
Mirzaie, Ali
NANOTECHNOLOGY REVIEWS, 2018, 7 (01) : 43 - 68
[22] A dinuclear copper(I) thiodiacetate complex as an efficient and reusable click' catalyst for the synthesis of glycoconjugates
Sareen, Neha
Singh, Anoop S.
Tiwari, Vinod K.
Kant, Rajni
Bhattacharya, Subrato
DALTON TRANSACTIONS, 2017, 46 (37) : 12705 - 12710
[23] Magnetically reusable nanocatalysts in biginelli synthesis of dihydropyrimidinones (DHPMs)
Kazemi, Mosstafa
SYNTHETIC COMMUNICATIONS, 2020, 50 (10) : 1409 - 1445
[24] A Novel Multicomponent Synthesis of Imidazole Derivatives via Copper(II) Phthalocyanine as a Reusable Catalyst
Chakko, Seena
Ramya, K.
Shinu, V. S.
Arun, S.
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2023, 59 (12) : 2200 - 2204
[25] Annulation of N,N-dimethylanilines and maleimides catalyzed by reusable copper ferrite nanoparticles
Pham, Hai H.
Nguyen, An C. D.
Nguyen, Cao T. D.
Phan, Nam T. S.
Nguyen, Tung T.
TETRAHEDRON LETTERS, 2022, 107
[26] Three-component synthesis of a polysubstituted pyrrole core containing heterocyclic scaffolds over magnetically separable nanocrystalline copper ferrite
Paul, Sanjay
Pal, Gargi
Das, Asish R.
RSC ADVANCES, 2013, 3 (23): : 8637 - 8644
[27] CuFe2O4 nanoparticles: a magnetically recoverable and reusable catalyst for the synthesis of 5-substituted 1H-tetrazoles
Sreedhar, B.
Kumar, A. Suresh
Yada, Divya
TETRAHEDRON LETTERS, 2011, 52 (28) : 3565 - 3569
[28] Greener synthesis of 1,2,3-triazoles using a copper(i)-exchanged magnetically recoverable β-zeolite as catalyst
Costa, Elizama R.
Andrade, Floyd C. D.
de Albuquerque, Danilo Yano
Ferreira, Luanne E. M.
Lima, Thiago M.
Lima, Carolina G. S.
Silva, Domingos S. A.
Urquieta-Gonzalez, Ernesto A.
Paixao, Marcio W.
Schwab, Ricardo S.
NEW JOURNAL OF CHEMISTRY, 2020, 44 (35) : 15046 - 15053
[29] Supramolecular β-Cyclodextrin as a Reusable Catalyst for Xanthene Synthesis in Aqueous Medium
Mohamadpour, Farzaneh
ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 2023, 55 (04) : 317 - 325
[30] Oxidative degradation of organic pollutants using reusable catalyst
Bondarde, Mahesh P.
Lokhande, Kshama D.
Bhakare, Madhuri A.
Dhumal, Pratik S.
Some, Surajit
APPLIED NANOSCIENCE, 2022, 13 (6) : 4407 - 4414

← 1 2 3 4 5 →