Platinum-Catalyzed C-H Functionalization

被引：201
作者：
Labinger, Jay A. [1 ]
机构：
[1] CALTECH, Beckman Inst, Pasadena, CA 91125 USA
来源：
CHEMICAL REVIEWS | 2017年 / 117卷 / 13期
关键词：
BOND ACTIVATION; PT-II; REDUCTIVE ELIMINATION; OXIDATIVE FUNCTIONALIZATION; COMPLEXES; METHANE; METAL; LIGANDS; METHYL; PLATINACYCLES;
D O I：
10.1021/acs.chemrev.6b00583
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Recent developments in C-H bond activation and functionalization by Pt complexes are surveyed. Topics include the following: fundamental mechanistic investigations of C-H activation; stoichiometric intra- and intermolecular C-H activation; reactions of dioxygen with Pt(II) complexes that may be relevant to substrate oxygenation; and both stoichiometric and catalytic formation of C-O, C-C, and C-B bonds via C-H activation. Current interests and trends are discussed, both in the context of historical work and to forecast future directions and opportunities for the field.
引用
收藏
页码：8483 / 8496
页数：14
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