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Platinum-Catalyzed C-H Functionalization
被引:200
作者:
Labinger, Jay A.
[1
]
机构:
[1] CALTECH, Beckman Inst, Pasadena, CA 91125 USA
关键词:
BOND ACTIVATION;
PT-II;
REDUCTIVE ELIMINATION;
OXIDATIVE FUNCTIONALIZATION;
COMPLEXES;
METHANE;
METAL;
LIGANDS;
METHYL;
PLATINACYCLES;
D O I:
10.1021/acs.chemrev.6b00583
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Recent developments in C-H bond activation and functionalization by Pt complexes are surveyed. Topics include the following: fundamental mechanistic investigations of C-H activation; stoichiometric intra- and intermolecular C-H activation; reactions of dioxygen with Pt(II) complexes that may be relevant to substrate oxygenation; and both stoichiometric and catalytic formation of C-O, C-C, and C-B bonds via C-H activation. Current interests and trends are discussed, both in the context of historical work and to forecast future directions and opportunities for the field.
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页码:8483 / 8496
页数:14
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