Platinum-Catalyzed C-H Functionalization

被引:198
作者
Labinger, Jay A. [1 ]
机构
[1] CALTECH, Beckman Inst, Pasadena, CA 91125 USA
关键词
BOND ACTIVATION; PT-II; REDUCTIVE ELIMINATION; OXIDATIVE FUNCTIONALIZATION; COMPLEXES; METHANE; METAL; LIGANDS; METHYL; PLATINACYCLES;
D O I
10.1021/acs.chemrev.6b00583
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Recent developments in C-H bond activation and functionalization by Pt complexes are surveyed. Topics include the following: fundamental mechanistic investigations of C-H activation; stoichiometric intra- and intermolecular C-H activation; reactions of dioxygen with Pt(II) complexes that may be relevant to substrate oxygenation; and both stoichiometric and catalytic formation of C-O, C-C, and C-B bonds via C-H activation. Current interests and trends are discussed, both in the context of historical work and to forecast future directions and opportunities for the field.
引用
收藏
页码:8483 / 8496
页数:14
相关论文
共 50 条
[22]   Palladium-Catalyzed Directed para C-H Functionalization of Phenols [J].
Patra, Tuhin ;
Bag, Sukdev ;
Kancherla, Rajesh ;
Mondal, Anirban ;
Dey, Aniruddha ;
Pimparkar, Sandeep ;
Agasti, Soumitra ;
Modak, Atanu ;
Maiti, Debabrata .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (27) :7751-7755
[23]   Ru-Catalyzed Selective C-H Functionalization of Pyridotriazoles with Acrylates [J].
Joshi, Abhisek ;
Semwal, Rashmi ;
Adimurthy, Subbarayappa .
SYNOPEN, 2021, 05 (04) :294-300
[24]   Functionalization of Porphyrins Using Metal-Catalyzed C-H Activation [J].
Kiselev, Aleksey N. ;
Syrbu, Sergey A. ;
Lebedeva, Natalia Sh ;
Gubarev, Yury A. .
INORGANICS, 2022, 10 (05)
[25]   Rhodium(I)-Catalyzed Direct Enantioselective C-H Functionalization of Indoles [J].
Zhu, Dong-Xing ;
Xu, Ming-Hua .
JOURNAL OF ORGANIC CHEMISTRY, 2023, 88 (12) :7844-7848
[26]   Pd(ii)-catalyzed selective β-C-H functionalization of azobenzene carboxamides [J].
Padmavathi, Rayavarapu ;
Babu, Srinivasarao Arulananda .
ORGANIC & BIOMOLECULAR CHEMISTRY, 2023, 21 (13) :2689-2694
[27]   Nickel(II)/Salox-Catalyzed Enantioselective C-H Functionalization [J].
Chen, Jia-Hao ;
Yao, Qi-Jun ;
Zhong, Ming-Yu ;
Jiang, Tian-Yu ;
Huang, Fan-Rui ;
Li, Xiang ;
Shi, Bing-Feng .
ACS CENTRAL SCIENCE, 2025, 11 (01) :127-135
[28]   Heterocycle Formation via Palladium-Catalyzed C-H Functionalization [J].
Mei, Tian-Sheng ;
Kou, Lei ;
Ma, Sandy ;
Engle, Keary M. ;
Yu, Jin-Quan .
SYNTHESIS-STUTTGART, 2012, 44 (12) :1778-1791
[29]   Pd-Catalyzed Direct and Selective C-H Functionalization: C3-Acetoxylation of Indoles [J].
Liu, Qiang ;
Li, Gang ;
Yi, Hong ;
Wu, Pan ;
Liu, Jie ;
Lei, Aiwen .
CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (08) :2353-2357
[30]   C-H functionalization of tetramethylsilane employing a borylnitrene [J].
Mueller, Matthias ;
Maichle-Moessmer, Caecilia ;
Bettinger, Holger F. .
CHEMICAL COMMUNICATIONS, 2013, 49 (100) :11773-11775