Highly efficient CO2 capture by carbonyl-containing ionic liquids through Lewis acid-base and cooperative C-H•••O hydrogen bonding interaction strengthened by the anion

被引:72
作者
Ding, Fang [1 ]
He, Xi [1 ]
Luo, Xiaoyan [1 ]
Lin, Wenjun [1 ]
Chen, Kaihong [1 ]
Li, Haoran [1 ,2 ]
Wang, Congmin [1 ]
机构
[1] Zhejiang Univ, Dept Chem, ZJU NHU United R&D Ctr, Hangzhou 310027, Zhejiang, Peoples R China
[2] Zhejiang Univ, Dept Chem & Biol Engn, State Key Lab Chem Engn, Hangzhou 310027, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
SO2; ABSORPTION; BASICITY;
D O I
10.1039/c4cc06944g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A strategy to improve CO2 capture significantly through the non-covalent interaction strengthened by the anion was reported, which exhibits an extremely high capacity up to 1.24 mole CO2 per mole ionic liquid and excellent reversibility due to the presence of the enhanced Lewis acid-base and cooperative C-H center dot center dot center dot O hydrogen bonding interactions.
引用
收藏
页码:15041 / 15044
页数:4
相关论文
共 42 条
[31]   How strong is the Cα-H•••O=C hydrogen bond? [J].
Vargas, R ;
Garza, J ;
Dixon, DA ;
Hay, BP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (19) :4750-4755
[32]   The structure of r(UUCGCG) has a 5'-UU-overhang exhibiting Hoogsteen-like trans U center dot U base pairs [J].
Wahl, MC ;
Rao, ST ;
Sundaralingam, M .
NATURE STRUCTURAL BIOLOGY, 1996, 3 (01) :24-31
[33]   Tuning the Basicity of Ionic Liquids for Equimolar CO2 Capture [J].
Wang, Congmin ;
Luo, Xiaoyan ;
Luo, Huimin ;
Jiang, De-en ;
Li, Haoran ;
Dai, Sheng .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (21) :4918-4922
[34]   Highly efficient CO2 capture by tunable alkanolamine-based ionic liquids with multidentate cation coordination [J].
Wang, Congmin ;
Guo, Yan ;
Zhu, Xiang ;
Cui, Guokai ;
Li, Haoran ;
Dai, Sheng .
CHEMICAL COMMUNICATIONS, 2012, 48 (52) :6526-6528
[35]   Tuning the Physicochemical Properties of Diverse Phenolic Ionic Liquids for Equimolar CO2 Capture by the Substituent on the Anion [J].
Wang, Congmin ;
Luo, Huimin ;
Li, Haoran ;
Zhu, Xiang ;
Yu, Bo ;
Dai, Sheng .
CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (07) :2153-2160
[36]   Highly Efficient and Reversible SO2 Capture by Tunable Azole-Based Ionic Liquids through Multiple-Site Chemical Absorption [J].
Wang, Congmin ;
Cui, Guokai ;
Luo, Xiaoyan ;
Xu, Yingjie ;
Li, Haoran ;
Dai, Sheng .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (31) :11916-11919
[37]   Carbon Dioxide Capture by Superbase-Derived Protic Ionic Liquids [J].
Wang, Congmin ;
Luo, Huimin ;
Jiang, De-en ;
Li, Haoran ;
Dai, Sheng .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (34) :5978-5981
[38]  
Wasserscheid P, 2000, ANGEW CHEM INT EDIT, V39, P3772, DOI 10.1002/1521-3773(20001103)39:21<3772::AID-ANIE3772>3.0.CO
[39]  
2-5
[40]   Desulfurization of flue gas:: SO2 absorption by an ionic liquid [J].
Wu, WZ ;
Han, BX ;
Gao, HX ;
Liu, ZM ;
Jiang, T ;
Huang, J .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (18) :2415-2417