Synthesis of Zero-Valent Iron Nanoparticles Via Electrical Wire Explosion for Efficient Removal of Heavy Metals

被引:13
作者
Seyedi, Seyed Mojtaba [1 ,2 ]
Rabiee, Hesamoddin [3 ]
Shahabadi, Seyed Mahdi Seyed [3 ]
Borghei, Seyed Mehdi [2 ]
机构
[1] PNF Co, Dept Res & Dev, Tehran, Iran
[2] Sharif Univ Technol, Dept Chem & Petr Engn, Azadi St, Tehran 1136511155, Iran
[3] Islamic Azad Univ, Young Researchers & Elites Club, North Tehran Branch, Tehran, Iran
关键词
Adsorption; Heavy metal removal; Nanoparticles; Wastewater treatment; NANOSCALE ZEROVALENT IRON; WASTE-WATER; HEXAVALENT CHROMIUM; AQUEOUS-SOLUTION; CHITOSAN BEADS; REMEDIATION; KINETICS; CR(VI); SHELL; NZVI;
D O I
10.1002/clen.201600139
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In this paper, electrical wire explosion (EWE) was used as a simple, clean, in situ method to synthesise nano zero-valent iron (nZVI) particles in liquid mediums. The structural and physical properties of the synthesised nZVI particles were characterised by x-ray diffraction, Brunauer-Emmett-Teller analysis, field emission scanning electron microscopy and transmission electron microscopy. The synthesised spherical nanoparticles, at a specific size of 10-50 nm, possessed large surface areas of approximately 13.27m(2)/g, reinforcing the significant advantages of EWE, that is, less aggregation and in situ production of nanoparticles with enhanced removal efficacy, for groundwater treatment. After 1 h the adsorption capacity for Cr(VI), Ni(II), and Cd(II) (Q(60) = C-ions/C-iron (mg/g)) at pH 4 was approximately 143.4 (89.0%), 137.5 (79.0%), and 132.6 mg/g (72.0%), respectively. The effect of temperature was also examined at initial metal ions concentration of 70 mg/L, nZVI dosage of 0.2 g/L and pH 4. The results showed 45 degrees C was the optimum temperature for adsorption of Cr(VI), Ni(II), and Cd(II) ions, and over a 60-min period at this temperature adsorption capacity increased to 153.56 (95.3%), 158.91 (91.3%), and 163.90 mg/g (89.0%), respectively.
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页数:9
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