Bis(triethylammonium) tetrachloridomanganate(II)

被引：5

作者：

Clegg, William ^{[1
]}

Martin, Nicola C. ^{[1
]}

机构：

[1] Univ Newcastle Upon Tyne, Sch Nat Sci Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536807012317

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, (Et3NH)(2)[MnCl4], was obtained unexpectedly in an attempt to prepare a carboxylate-bridged coordination network. It is the first reported structure of a tertiary ammonium salt of the tetrahedral [MnCl4](2-) anion (Table 1). Each of the two crystallographically independent cations forms an N - H (...) Cl hydrogen bond to the anion (Table 2), generating discrete ion triples. The Mn - Cl bonds involving the hydrogen-bonded Cl atoms are longer than the others.

引用

页码：M1151 / U149

页数：10