Production of biodiesel by ultrasound assisted esterification of Oreochromis niloticus oil

被引：82

作者：

Santos, Francisco F. P. ^{[1
]}

Malveira, Jackson Q. ^{[2
]}

Cruz, Marcia G. A. ^{[1
]}

Fernandes, Fabiano A. N. ^{[1
]}

机构：

[1] Univ Fed Ceara, Dept Engn Quim, BR-60455760 Fortaleza, Ceara, Brazil

[2] NUTEC Fundacao Nucleo Tecnol Ind Ceara, BR-60451970 Fortaleza, Ceara, Brazil

来源：

FUEL | 2010年 / 89卷 / 02期

关键词：

Methyl ester; Tilapia; Oreochromis niloticus; Esterification; Methanolysis; FREE FATTY-ACIDS; METHYL-ESTERS; PALM OIL; TRANSESTERIFICATION; CONVERSION; CATALYST;

D O I：

10.1016/j.fuel.2009.05.030

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

This paper evaluates the production of methyl esters from Oreochromis niloticus (Nile tilapia) oil and methanol. The reaction was carried out applying low-frequency high-intensity ultrasound (40 kHz) under atmospheric pressure and ambient temperature. Response surface methodology (RSM) was used to evaluate the influence of alcohol to oil molar ratio, catalyst concentration (sulfuric acid) and temperature on the yield of O. niloticus oil into methyl esters. Analysis of the operating conditions by RSM showed that the most important operating condition affecting the reaction was the alcohol to FFA molar ratio. The highest yield observed was of 98.2% after 90 min of reaction. The optimal operating condition was obtained applying an alcohol to oil molar ratio of 9.0 and a catalyst concentration of 2.0% w/w and temperature of 30 degrees C. (c) 2009 Elsevier Ltd. All rights reserved.

引用

页码：275 / 279

页数：5

共 25 条

[1] Experimental evaluation of the transesterification of waste palm oil into biodiesel [J].

Al-Widyan, MI ;

Al-Shyoukh, AO .

BIORESOURCE TECHNOLOGY, 2002, 85 (03) :253-256

[2] Optimisation of biodiesel production by sunflower oil transesterification [J].

Antolín, G ;

Tinaut, FV ;

Briceño, Y ;

Castaño, V ;

Pérez, C ;

Ramírez, AI .

BIORESOURCE TECHNOLOGY, 2002, 83 (02) :111-114

[3] Acid-catalyzed homogeneous esterification reaction for biodiesel production from palm fatty acids [J].

Aranda, Donato A. G. ;

Santos, Rafael T. P. ;

Tapanes, Neyda C. O. ;

Ramos, Andre Luis Dantas ;

Antunes, Octavio Auqusto C. .

CATALYSIS LETTERS, 2008, 122 (1-2) :20-25

[4] A kinetic study of the esterification of free fatty acids (FFA) in sunflower oil [J].

Berrios, M. ;

Siles, J. ;

Martin, M. A. ;

Martin, A. .

FUEL, 2007, 86 (15) :2383-2388

[5]

Chiou BS, 2008, T ASABE, V51, P797, DOI 10.13031/2013.24517

[6] Biodiesel production by esterification of palm fatty acid distillate [J].

Chongkhong, S. ;

Tongurai, C. ;

Chetpattananondh, P. ;

Bunyakan, C. .

BIOMASS & BIOENERGY, 2007, 31 (08) :563-568

[7] Kinetics of palm oil transesterification in a batch reactor [J].

Darnoko, D ;

Cheryan, M .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2000, 77 (12) :1263-1267

[8] VARIABLES AFFECTING THE YIELDS OF FATTY ESTERS FROM TRANSESTERIFIED VEGETABLE-OILS [J].

FREEDMAN, B ;

PRYDE, EH ;

MOUNTS, TL .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1984, 61 (10) :1638-1643

[9] Biodiesel production through transesterification of triolein with various alcohols in an ultrasonic field [J].

Hanh, Hoang Duc ;

Nguyen The Dong ;

Okitsu, Kenji ;

Nishimura, Rokuro ;

Maeda, Yasuaki .

RENEWABLE ENERGY, 2009, 34 (03) :766-768

[10] PREPARATION OF FATTY-ACID METHYL ESTERS FOR GAS-CHROMATOGRAPHIC ANALYSIS OF LIPIDS IN BIOLOGICAL-MATERIALS [J].

LIU, KS .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1994, 71 (11) :1179-1187

← 1 2 3 →