Synthesis of 5-amino-6-nitro-1,2,3,4-tetrazine 1,3-dioxide

被引：12
|
作者：
Guskov, A. A. [1 ]
Klenov, M. S. [1 ]
Churakov, A. M. [1 ]
Tartakovsky, V. A. [1 ]
机构：
[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, 47 Leninsky Prosp, Moscow 119991, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2016年 / 65卷 / 11期
基金：
俄罗斯科学基金会;
关键词：
1,2,3,4-tetrazine 1,3-dioxides; electrophilic substitution; energetic compounds; C-13 and N-14 NMR spectroscopy; ISO-DTTO; DESIGN;
D O I：
10.1007/s11172-016-1650-2
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
5-Amino-(tert-butyl-NNO-azoxy)-1,2,3,4-tetrazine 1,3-dioxide reacts with nitronium tetra-fluoroborate to give 5-amino-6-nitro-1,2,3,4-tetrazine 1,3-dioxide. This compound is of interest as a new energetic material. A plausible reaction mechanism involves electrophilic substitution of the tert-butyl-NNO-azoxy group by the nitro group.
引用
收藏
页码：2763 / 2765
页数：3
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