Mercury(II) complexes of pyrrolidinedithiocarbamate, crystal structure of bis{[μ2-(pyrrolidinedithiocarbamato-S,S′)(pyrrolidinedithiocarbamato-S,S′)mercury(II)]}

被引：19

作者：

Altaf, Muhammad ^{[2
]}

Stoeckli-Evans, Helen ^{[2
]}

Batool, Syeda Shahzadi ^{[1
]}

Isab, Anvarhusein A. ^{[3
]}

Ahmad, Saeed ^{[1
]}

Saleem, Muhammad ^{[4
]}

Awan, Shafique Ahmad ^{[4
]}

Shaheen, Muhammad Ashraf ^{[5
]}

机构：

[1] Univ Engn & Technol, Dept Chem, Lahore 54890, Pakistan

[2] Univ Neuchatel, Inst Phys, CH-2009 Neuchatel, Switzerland

[3] King Fahd Univ Petr & Minerals, Dept Chem, Dhahran 31261, Saudi Arabia

[4] PAEC, Islamabad, Pakistan

[5] Univ Sargodha, Dept Chem, Sargodha, Pakistan

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2010年 / 63卷 / 07期

关键词：

Mercury(II); Pyrrolidinedithiocarbamate; Crystal structure; X-RAY-STRUCTURE; PYRROLIDINE DITHIOCARBAMATE; MOLECULAR-STRUCTURE; SOLVENT-EXTRACTION; NMR-SPECTRA; KAPPA-B; ZINC; HG; VULCANIZATION; ACTIVATION;

D O I：

10.1080/00958971003759085

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mercury(II) complexes of pyrrolidinedithiocarbamate (PDTC) having the general formula [Hg(PDTC)X] (X = Cl-, SCN-, and CN-) and [Hg(PDTC)(2)] have been prepared and characterized by elemental analysis, IR, and NMR. The crystal structure of [Hg(PDTC)(2)] has also been determined by X-ray crystallography, showing that the complex is a centrosymmetric dimer, [Hg-2(PDTC)(4)] (bis[mu(2)-(pyrrolidinedithiocarbamato-S,S')(pyrrolidinedithiocarbamato-S,S')mercury(II)]) (1). The solid-state structure of 1 contains two crystallographically equivalent Hg(II) centers in a distorted tetrahedron.

引用

页码：1176 / 1185

页数：10

共 50 条

[11]

Cox MJ, 2000, MAIN GROUP MET CHEM, V23, P793

[12] Structural variations in the mercury(II) bis(1,1-dithiolate)s: the crystal and molecular structure of [Hg(S2CNMe2)(2)] [J].