Mercury(II) complexes of pyrrolidinedithiocarbamate, crystal structure of bis{[μ2-(pyrrolidinedithiocarbamato-S,S′)(pyrrolidinedithiocarbamato-S,S′)mercury(II)]}

被引：19
作者：
Altaf, Muhammad [2 ]
Stoeckli-Evans, Helen [2 ]
Batool, Syeda Shahzadi [1 ]
Isab, Anvarhusein A. [3 ]
Ahmad, Saeed [1 ]
Saleem, Muhammad [4 ]
Awan, Shafique Ahmad [4 ]
Shaheen, Muhammad Ashraf [5 ]
机构：
[1] Univ Engn & Technol, Dept Chem, Lahore 54890, Pakistan
[2] Univ Neuchatel, Inst Phys, CH-2009 Neuchatel, Switzerland
[3] King Fahd Univ Petr & Minerals, Dept Chem, Dhahran 31261, Saudi Arabia
[4] PAEC, Islamabad, Pakistan
[5] Univ Sargodha, Dept Chem, Sargodha, Pakistan
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2010年 / 63卷 / 07期
关键词：
Mercury(II); Pyrrolidinedithiocarbamate; Crystal structure; X-RAY-STRUCTURE; PYRROLIDINE DITHIOCARBAMATE; MOLECULAR-STRUCTURE; SOLVENT-EXTRACTION; NMR-SPECTRA; KAPPA-B; ZINC; HG; VULCANIZATION; ACTIVATION;
D O I：
10.1080/00958971003759085
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Mercury(II) complexes of pyrrolidinedithiocarbamate (PDTC) having the general formula [Hg(PDTC)X] (X = Cl-, SCN-, and CN-) and [Hg(PDTC)(2)] have been prepared and characterized by elemental analysis, IR, and NMR. The crystal structure of [Hg(PDTC)(2)] has also been determined by X-ray crystallography, showing that the complex is a centrosymmetric dimer, [Hg-2(PDTC)(4)] (bis[mu(2)-(pyrrolidinedithiocarbamato-S,S')(pyrrolidinedithiocarbamato-S,S')mercury(II)]) (1). The solid-state structure of 1 contains two crystallographically equivalent Hg(II) centers in a distorted tetrahedron.
引用
收藏
页码：1176 / 1185
页数：10
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