Application of Ru(II)porphyrin complexes as epoxidation catalyst of olefins

被引：12

作者：

Babakhania, Rezvan ^{[1
]}

Bahadoran, Farzad ^{[1
]}

Safari, Nasser ^{[1
]}

机构：

[1] Shahid Beheshti Univ Med Sci, Dept Chem, Tehran 1983963113, Iran

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2007年 / 11卷 / 02期

关键词：

ruthenium porphyrin; epoxidation; catalysis;

D O I：

10.1142/S1088424607000126

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two complexes of ruthenium(II) carbonyl tetraphenyl- and tetramesytilporphyrins were used as catalysts for epoxidation of olefins using metachloroperbenzoic acid and iodosylbenzene, as oxidants. Better results were obtained with the (TPP)RuCO catalyst in the presence of metachloroperbenzoic acid; however, iodosylbenzene showed higher yields than metachloroperbenzoic acid for some aromatic olefins. The effect of imidazole axial base was also investigated. Two different pathways are proposed based on these two oxygen atom transfer agents. Copyright (c) 2007 Society of Porphyrins & Phthalocyanines.

引用

页码：95 / 99

页数：5

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