ZnFe2O4@C/graphene nanocomposites as excellent anode materials for lithium batteries

被引:89
作者
Lin, Li [1 ]
Pan, Qinmin [1 ]
机构
[1] Harbin Inst Technol, State Key Lab Robot & Syst, Sch Chem Engn & Technol, Harbin 150001, Peoples R China
基金
中国国家自然科学基金;
关键词
NANOCRYSTALLINE ZNFE2O4; ELECTRODE PERFORMANCE; CARBON; NANOPARTICLES; COMPOSITES; PRECURSOR; DOPAMINE; HYBRIDS; STORAGE; SPHERES;
D O I
10.1039/c4ta05368k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
ZnFe2O4 is a promising anode material for lithium ion batteries (LIBs) because of its high theoretical capacity (1000.5 mA h g(-1)), but its practical application is impeded by fast capacity fading and poor rate capability. To overcome these limitations, herein, core-shell structured ZnFe2O4@C nanoparticles were homogeneously anchored onto the surface of graphene (G) nanosheets through a mussel-inspired process and subsequent calcinations. The resulting ZnFe2O4@C/G nanocomposite delivered a reversible capacity of 705 mA h g(-1) at 0.25 C after 180 cycles (with capacity retention of 99.4%), and high rate capability of 403.5 mA h g(-1) at 5 C, thus exhibiting one of the best lithium storage properties among the reported ZnFe2O4 anodes. The excellent electrochemical performance is mainly related to the conducting, buffering and protective effects of carbon shells and graphene nanosheets on ZnFe2O4 nanoparticles. Considering its simplicity and effectiveness, this strategy might be extended to other anode materials with intrinsically low electronic conductivity, large volume-variation and severe agglomeration in the process of lithiation-delithiation.
引用
收藏
页码:1724 / 1729
页数:6
相关论文
共 35 条
[1]   Carbon Coated ZnFe2O4 Nanoparticles for Advanced Lithium-Ion Anodes [J].
Bresser, Dominic ;
Paillard, Elie ;
Kloepsch, Richard ;
Krueger, Steffen ;
Fiedler, Martin ;
Schmitz, Rene ;
Baither, Dietmar ;
Winter, Martin ;
Passerini, Stefano .
ADVANCED ENERGY MATERIALS, 2013, 3 (04) :513-523
[2]   Nanomaterials for rechargeable lithium batteries [J].
Bruce, Peter G. ;
Scrosati, Bruno ;
Tarascon, Jean-Marie .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (16) :2930-2946
[3]   Monodisperse magnetic single-crystal ferrite microspheres [J].
Deng, H ;
Li, XL ;
Peng, Q ;
Wang, X ;
Chen, JP ;
Li, YD .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (18) :2782-2785
[4]   One-pot synthesis of ZnFe2O4/C hollow spheres as superior anode materials for lithium ion batteries [J].
Deng, Yuanfu ;
Zhang, Qiumei ;
Tang, Shidi ;
Zhang, Leiting ;
Deng, Shengnan ;
Shi, Zhicong ;
Chen, Guohua .
CHEMICAL COMMUNICATIONS, 2011, 47 (24) :6828-6830
[5]   High capacity ZnFe2O4 anode material for lithium ion batteries [J].
Ding, Yu ;
Yang, Yifu ;
Shao, Huixia .
ELECTROCHIMICA ACTA, 2011, 56 (25) :9433-9438
[6]   Lithium storage in hollow spherical ZnFe2O4 as anode materials for lithium ion batteries [J].
Guo, Xianwei ;
Lu, Xia ;
Fang, Xiangpeng ;
Mao, Ya ;
Wang, Zhaoxiang ;
Chen, Liquan ;
Xu, Xiaoxue ;
Yang, Hong ;
Liu, Yinong .
ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (06) :847-850
[7]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339
[8]   Mussel-inspired surface chemistry for multifunctional coatings [J].
Lee, Haeshin ;
Dellatore, Shara M. ;
Miller, William M. ;
Messersmith, Phillip B. .
SCIENCE, 2007, 318 (5849) :426-430
[9]   Dopamine as the coating agent and carbon precursor for the fabrication of N-doped carbon coated Fe3O4 composites as superior lithium ion anodes [J].
Lei, Cheng ;
Han, Fei ;
Li, Duo ;
Li, Wen-Cui ;
Sun, Qiang ;
Zhang, Xiang-Qian ;
Lu, An-Hui .
NANOSCALE, 2013, 5 (03) :1168-1175
[10]   Co3O4@graphene Composites as Anode Materials for High-Performance Lithium Ion Batteries [J].
Li, Baojun ;
Cao, Huaqiang ;
Shao, Jin ;
Li, Guoqiang ;
Qu, Meizhen ;
Yin, Gui .
INORGANIC CHEMISTRY, 2011, 50 (05) :1628-1632