Thermal expansion of solids: review on theories

被引：68
作者：
Drebushchak, V. A. [1 ,2 ]
机构：
[1] RAS, SB, VS Sobolev Inst Geol & Mineral, Pr Ak Koptyuga 3, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Pirogova 2, Novosibirsk 630090, Russia
来源：
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2020年 / 142卷 / 02期
关键词：
Anharmonicity; Gruneisen; Heat capacity; Interatomic potential; Thermal expansion; EQUATION-OF-STATE; GRUNEISEN-PARAMETER; HEAT-CAPACITY; ISOTHERMAL COMPRESSIBILITY; THERMODYNAMIC PROPERTIES; PRESSURE-DEPENDENCE; DEGREES-K; TEMPERATURE; LATTICE; SODIUM;
D O I：
10.1007/s10973-020-09370-y
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The coefficient of thermal expansion of a solid can be derived from (1) anharmonicity of atomic vibrations; (2) lattice dynamics; (3) equation of state by G. Mie; (4) equation of state by E. Gruneisen; and (6) potential of interatomic interaction. Only the last theory in this list provides us with the equation describing correctly all features in the thermal expansion: (1) proportionality between thermal expansion and heat capacity; (2) various values of "plateau" for the coefficient of thermal expansion at temperatures close to Debye temperature; and (3) acceleration of the thermal expansion in the vicinity of melting point.
引用
收藏
页码：1097 / 1113
页数：17
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