Polyhalomethanes combined with lewis acids in alkane chemistry

被引：43
作者：
Akhrem, Irena [1 ]
Orlinkov, Alexander [1 ]
机构：
[1] Russian Acad Sci, Inst Organoelement Cpds, Moscow 117813, Russia
来源：
CHEMICAL REVIEWS | 2007年 / 107卷 / 05期
关键词：
D O I：
10.1021/cr970005n
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An overview is given of a new family of aprotic organic superelectrophiles for effective functionalizations, of alkanes and cycloalkanes. Focus is on polyhalomethanes combined with Lewis acids. Specific topics covered include polyhalomethane-SbF5-mediated transformations of alkanes and cycloalkanes, polyhalomethanes combined with aluminum halides as a novel family of aprotic organic superelectrophiles for alkane and cycloalkane transformations, and mechanistic studies of the reactions of alkanes with polyhalomethane-based superelectrophiles.
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收藏
页码：2037 / 2079
页数：43
相关论文
共 537 条
[1]   Correlation of gas-phase stability of bridgehead carbocations with rates of solvolysis and ab initio calculations [J].
Abboud, JLM ;
Castano, O ;
Della, EW ;
Herreros, M ;
Muller, P ;
Notario, R ;
Rossier, JC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (09) :2262-2266
[2]  
Ahlberg P, 2001, CHEM-EUR J, V7, P1936, DOI 10.1002/1521-3765(20010504)7:9<1936::AID-CHEM1936>3.0.CO
[3]  
2-T
[4]  
Ahlberg P, 2001, CHEM-EUR J, V7, P2501, DOI 10.1002/1521-3765(20010618)7:12<2501::AID-CHEM25011>3.0.CO
[5]  
2-W
[6]   DIRECT ALKYLACYLATION OF ARENES BY ALKANES AND CYCLOALKANES IN THE PRESENCE OF APROTIC SUPERACIDS [J].
AKHREM, I ;
ORLINKOV, A ;
VOLPIN, M .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (03) :257-258
[7]   First examples of superelectrophile initiated iodination of alkanes and cycloalkanes [J].
Akhrem, I ;
Orlinkov, A ;
Vitt, S ;
Chistyakov, A .
TETRAHEDRON LETTERS, 2002, 43 (07) :1333-1335
[8]   An effective formylation of adamantane with CO initiated by the aprotic organic superacid CBr4 center dot 2AlBr(3) under mild conditions [J].
Akhrem, I ;
Churilova, I ;
Bernadyuk, S ;
Volpin, M .
TETRAHEDRON LETTERS, 1996, 37 (32) :5775-5778
[9]   Unprecedented facile reactions of propane and cycloalkanes with elemental sulfur leading to dialkylsulfides and dicycloalkylsulfides [J].
Akhrem, I ;
Orlinkov, A ;
Vitt, S .
INORGANICA CHIMICA ACTA, 1998, 280 (1-2) :355-359
[10]   A NOVEL FAMILY OF APROTIC ORGANIC SUPERACIDS FOR LOW-TEMPERATURE ALKANE AND CYCLOALKANE TRANSFORMATIONS [J].
AKHREM, I ;
ORLINKOV, A ;
VOLPIN, M .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (08) :671-672
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