Polyhalomethanes combined with lewis acids in alkane chemistry

被引：43

作者：

Akhrem, Irena ^{[1
]}

Orlinkov, Alexander ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Organoelement Cpds, Moscow 117813, Russia

来源：

CHEMICAL REVIEWS | 2007年 / 107卷 / 05期

关键词：

D O I：

10.1021/cr970005n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An overview is given of a new family of aprotic organic superelectrophiles for effective functionalizations, of alkanes and cycloalkanes. Focus is on polyhalomethanes combined with Lewis acids. Specific topics covered include polyhalomethane-SbF5-mediated transformations of alkanes and cycloalkanes, polyhalomethanes combined with aluminum halides as a novel family of aprotic organic superelectrophiles for alkane and cycloalkane transformations, and mechanistic studies of the reactions of alkanes with polyhalomethane-based superelectrophiles.

引用

页码：2037 / 2079

页数：43

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