Domain reversal in stoichiometric LiTaO3 prepared by vapor transport equilibration

被引:62
作者
Tian, L [1 ]
Gopalan, V
Galambos, L
机构
[1] Penn State Univ, Mat Res Inst, University Pk, PA 16802 USA
[2] Penn State Univ, Dept Mat Sci & Engn, University Pk, PA 16802 USA
[3] Stanford Univ, SSPL, Dept Elect Engn, Stanford, CA 94035 USA
关键词
D O I
10.1063/1.1814436
中图分类号
O59 [应用物理学];
学科分类号
摘要
Domain reversal in stoichiometric lithium tantalate (LiTaO3) single crystals prepared by vapor transport equilibrium (VTE) method was studied. Starting from a virgin VTE crystal and using water electrodes, the coercive fields were found to be 1.39+/-0.01 kV/cm and 1.23+/-0.01 kV/cm for the first poling and the second poling, respectively, indicating a built-in internal field of 0.08 kV/cm. The spontaneous polarization, P-s was 55.2+/-0.5 muC/cm(2) and the Curie temperature was T-c=701+/-2.5degreesC. The switching time, t(s), exhibits an exponential dependence on the external field, E with activation energy of 10.84+/-0.22 kV/cm. No domain backswitching was observed. These properties are dramatically different from those of congruent and even near-stoichiometric compositions of lithium tantalate grown by Czhochralski method. (C) 2004 American Institute of Physics.
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收藏
页码:4445 / 4447
页数:3
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