Sc2(pydc)2 unit based 1D, 2D and 3D metal-organic frameworks as heterogeneous Lewis acid catalysts for cyanosilylation

被引：34

作者：

Cao, Yu ^{[1
]}

Zhu, Ziqian ^{[1
]}

Xu, Jianing ^{[1
]}

Wang, Li ^{[1
]}

Sun, Jiayin ^{[2
]}

Chen, Xiaobo ^{[3
]}

Fan, Yong ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

[2] Anqing Normal Univ, Sch Chem & Chem Engn, Anqing 246011, Anhui, Peoples R China

[3] Monash Univ, Dept Mat Engn, Clayton, Vic 3800, Australia

来源：

DALTON TRANSACTIONS | 2015年 / 44卷 / 04期

关键词：

HYDROGEN STORAGE; CARBON-DIOXIDE; ADSORPTION; LIGAND; STABILITY;

D O I：

10.1039/c4dt03221g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three scandium metal-organic frameworks (Sc-MOFs), [Sc(pydc)(Hpydc)(H2O)]center dot H2O (1), [Sc-2(pydc)(3)(H2O)(4)]center dot 5H(2)O (2) and [Sc(pydc)(H2O)(NO3)] (3) with similar Sc-2(pydc)(2) building unit were prepared by using 2,3-pyridinedicarboxylic acid (H(2)pydc) ligand under hydrothermal conditions. Compound 1 exhibits a ladder-shaped chain with Sc-2(pydc)(2) units, which further construct a supramolecular characteristic with water molecules via hydrogen bond. Compound 2 features a waved layer made up of pydc(2)-ligands and two types of crystallographically different Sc(III) ions, among which Sc2 and pydc(2-) ligands constructed the Sc-2(pydc)(2) units. In compound 3, left and right helixes were alternately linked by the Sc-2(pydc)(2) units forming a hexagonal network with nbo-a topology. All the prepared compounds present effective heterogeneous Lewis acid catalytic functionality for the cyanosilylation of aldehyde.

引用

页码：1942 / 1947

页数：6

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